English

Complete the following reaction sequence by writing the structural formulae of the organic compound 'A', 'B' and 'C'. -2-Bromobutane→Alc⋅KOHA→BrA2B→NaNHA2C

Advertisements
Advertisements

Question

Complete the following reaction sequence by writing the structural formulae of the organic compound 'A', 'B' and 'C'.

\[\ce{2-Bromobutane->[Alc.KOH]A->[][Br2]B->[][NaNH2]C}\]

Short/Brief Note
Advertisements

Solution

\[\begin{array}{cc}
\phantom{.}\ce{Br}\phantom{................................................................}\ce{Br}\phantom{.............................................}\\
\phantom{...}|\phantom{..................................................................}|\phantom{................................................}\\
\ce{\underset{\text{2-Bromobutane}}{H3C - CH - CH2CH3}->[Alc.KOH][-KBr]\underset{\underset{(Major) (A)}{But-2-ene}}{H3C - CH = CH - CH3}->[Br2] H3C - CH - CH - CH3 ->[NaNH2][Double dehydrohalogen reaction] \underset{\text{But-2-yne (C)}}{H3C - C ≡ C-CH3}}\\
\phantom{.........}|\\
\phantom{................}\ce{\underset{\text{2,3-Dibromobutane (B)}}{Br}}
\end{array}\]
shaalaa.com
  Is there an error in this question or solution?
Chapter 10: Halogen Derivatives - Exercises [Page 233]

APPEARS IN

Balbharati Chemistry [English] Standard 12 Maharashtra State Board
Chapter 10 Halogen Derivatives
Exercises | Q 7. ii. a. | Page 233

RELATED QUESTIONS

from the following pair would undergo SN2 faster from the other?

a. CH3CH2CH2I      b. CH3CH2CH2Cl


Name the reagent used to bring about the following conversion.

Bromoethane to ethoxyethane


Name the reagent used to bring about the following conversion.

1-Chloropropane to 1-nitropropane


Name the reagent used to bring about the following conversion.

Chlorobenzene to biphenyl


Convert the following:

2-Chloropropane to propan-1-ol


HCl is added to a hydrocarbon ‘A’ \[\ce{(C4H8)}\] to give a compound ‘B’ which on hydrolysis with aqueous alkali forms tertiary alcohol ‘C’ \[\ce{(C4H10O)}\]. Identify ‘A’ ,‘B’ and ‘C’.


Observe the following and answer the question given below.

Comment on the bond length of C–X bond in it.


Propane nitrile can be prepared by heating ____________


Explain the factors affecting SN1 and SN2 mechanism.


What is dehydrohalogenation? State the rule for the formation of the preferred product of dehydrohalogenation.


In alkaline hydrolysis of tertiary butyl bromide, ____________.


Ethyl bromide undergoes the following reaction:

\[\ce{\underset{Ethyl bromide}{C2H5Br} + \underset{(aq.)}{KOH} ->[\Delta] \underset{Ethyl alcohol}{C2H5OH} + KBr}\]

Which of the following is a WRONG statement?


What type of hybridisation is present in carbocation formed during the alkaline hydrolysis of 1- bromo-1- phenyl ethane?


Which of the following carbocation is the most stable?


Which of the following is FALSE regarding SN2 reaction mechanism?


Identify major product 'B' in the following reaction.

\[\ce{But-1-ene ->[HBr][Peroxide] A ->[AgCN][\Delta] B}\]


Identify 'B' in the following reaction.

\[\ce{2-Bromobutane ->[KOH alc.][\Delta] A ->[HI] B}\]


Convert the following.

p-Nitrochlorobenzene to p-nitrophenol


Which of the following statements is incorrect regarding the dehydrohalogenation of alkenes?


With which halogen the reactions, of alkanes are explosive?


Observe the following and answer the questions given below:

Name the type of halogen derivative.


Complete the reaction:

\[\ce{CH3CH2Cl ->[AgCN][alc.\Delta]}\] ?


Complete the following reaction giving major product.

\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{..................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether]A}\\
|\phantom{..................}\\
\ce{CH3}\phantom{................}
\end{array}\]


Which of the following pair of compounds on heating gives butanenitrile?


Which of the following reagent is used for conversion of alkyl halide into nitrile?


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×