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The following mechanism has been proposed for the reaction of NO2 with F2 to form NO2F: NOX2X(g)+FX2X(g)⟶NOX2FX(g)+FX(g) (slow) FX(g)+NOX2X(g)⟶NOX2FX(g) (fast) The order of the reaction with

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Question

The following mechanism has been proposed for the reaction of NO2 with F2 to form NO2F:

\[\ce{NO2_{(g)} + F2_{(g)} -> NO2F_{(g)} + F_{(g)} (slow)}\]

\[\ce{F_{(g)} + NO2_{(g)} -> NO2F_{(g)} (fast)}\]

The order of the reaction with respect to NO2(g)

Options

  • 0

  • 3

  • 2

  • 1

MCQ
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Solution

1

Explanation:

The first step is the rate determining step because it is slow. The rate low is

rate = k [NO2] [F2]

As a result, the reaction order in relation to NO2(g) is 1.

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Chemical Properties of Halogen Derivatives
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