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Question
Complete the following reaction giving major products.
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Solution
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from the following pair would undergo SN2 faster from the other?
Complete the following reaction giving major products.
\[\ce{CH3 - CH = CH2 ->[HBr][peroxide] A ->[alc. KOH] B}\]
Arrange the following in the increasing order of boiling points.
- 1-Bromopropane
- 2- Bromopropane
- 1- Bromobutane
- 1-Bromo-2-methylpropane
Convert the following:
Propene to propan-1-ol
Convert the following:
2-Chloropropane to propan-1-ol
Convert the following:
tert-Butyl bromide to isobutyl bromide
Complete the following reaction sequence by writing the structural formulae of the organic compound 'A', 'B' and 'C'.
\[\ce{2-Bromobutane->[Alc.KOH]A->[][Br2]B->[][NaNH2]C}\]
Observe the following and answer the question given below.
Name the type of halogen derivative.
Observe the following and answer the question given below.
Comment on the bond length of C–X bond in it.
Observe the following and answer the question given below.
Can it react by SN1 mechanism? Justify your answer.
Propane nitrile can be prepared by heating ____________
Write the correct order of increasing ease of dehydrohalogenation.
\[\ce{\underset{\text{(I)}}{CH3 - CH2 - CH2 - Cl}}\]
\[\ce{\underset{\text{(II)}}{CH3 - CH(Cl) - CH3}}\]
\[\begin{array}{cc}
\ce{CH3}\\
|\\
\ce{CH3-C-Cl}\phantom{...}\\
|\\
\ce{CH3}\\
\ce{(III)}
\end{array}\]
What is dehydrohalogenation? State the rule for the formation of the preferred product of dehydrohalogenation.
The following mechanism has been proposed for the reaction of NO2 with F2 to form NO2F:
\[\ce{NO2_{(g)} + F2_{(g)} -> NO2F_{(g)} + F_{(g)} (slow)}\]
\[\ce{F_{(g)} + NO2_{(g)} -> NO2F_{(g)} (fast)}\]
The order of the reaction with respect to NO2(g)
Which one is most reactive towards nucleophilic addition reaction?
Identify major product 'B' in the following reaction.
\[\ce{But-1-ene ->[HBr][Peroxide] A ->[AgCN][\Delta] B}\]
Identify 'B' in the following reaction.
\[\ce{2-Bromobutane ->[KOH alc.][\Delta] A ->[HI] B}\]
Which of the following statements is incorrect regarding the dehydrohalogenation of alkenes?
The order of reactivity of the given haloalkanes towards nucleophiles is:
Observe the following and answer the questions given below:
Name the type of halogen derivative.
Complete the following reactions giving major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{.................}
\end{array}\]
Complete the following reaction giving major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{..................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether]A}\\
|\phantom{..................}\\
\ce{CH3}\phantom{................}
\end{array}\]
Give a reason for the following:
Ethoxy ethane with conc. HI at 373 K gives C2H5OH and CH3I but not CH3OH and C2H5I.
Complete the following reaction giving major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{................}\\
\end{array}\]
Which of the following pair of compounds on heating gives butanenitrile?
Identify the substrate 'X' in the following reaction.
\[\ce{\underset{}{X + O2} ->[i) Co-naphtenate 423 K][ii) dil HClΔ] \underset{\underset{}{}}{Phenol + Acetone}}\]
