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From the following pair would undergo SN2 faster from the other?

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प्रश्न

from the following pair would undergo SN2 faster from the other?

  1.    
एका वाक्यात उत्तर
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उत्तर

Compound (a) will undergo SN2 mechanism faster than (b).

Explanation:

  1. Sincey  is a primary halide it undergoes S2N reaction faster than .
  2. Since iodine is a better leaving group than chloride, 1-iodo propane (CH3CH2CH2I) undergoes S2N reaction faster than l-chloropropane (CH3CH2CH2CI).
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पाठ 10: Halogen Derivatives - Exercises [पृष्ठ २३२]

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बालभारती Chemistry [English] Standard 12 Maharashtra State Board
पाठ 10 Halogen Derivatives
Exercises | Q 2. iv. a. | पृष्ठ २३२

संबंधित प्रश्‍न

Complete the following reaction giving major products.

\[\begin{array}{cc}\ce{CH3 - CH = CH3 ->[Red P/Br2] A ->[Ag2O/H2O]B}\\|\phantom{.........................}\\
\ce{OH\phantom{.......................}}\end{array}\]


Name the reagent used to bring about the following conversion.

Ethyl bromide to ethyl isocyanide


Arrange the following in the increasing order of boiling points.

  1. 1-Bromopropane
  2. 2- Bromopropane
  3. 1- Bromobutane
  4. 1-Bromo-2-methylpropane

Distinguish between SN1 and SN2 mechanism of substitution reaction.


Convert the following:

Propene to propan-1-ol


Convert the following:

Ethanol to propane nitrile


Convert the following:

2-Chloropropane to propan-1-ol


The following will react faster by SN1 mechanism


Explain the factors affecting SN1 and SN2 mechanism.


Ethyl bromide undergoes the following reaction:

\[\ce{\underset{Ethyl bromide}{C2H5Br} + \underset{(aq.)}{KOH} ->[\Delta] \underset{Ethyl alcohol}{C2H5OH} + KBr}\]

Which of the following is a WRONG statement?


The following mechanism has been proposed for the reaction of NO2 with F2 to form NO2F:

\[\ce{NO2_{(g)} + F2_{(g)} -> NO2F_{(g)} + F_{(g)} (slow)}\]

\[\ce{F_{(g)} + NO2_{(g)} -> NO2F_{(g)} (fast)}\]

The order of the reaction with respect to NO2(g)


What type of hybridisation is present in carbocation formed during the alkaline hydrolysis of 1- bromo-1- phenyl ethane?


Which of the following is FALSE regarding SN2 reaction mechanism?


Identify major product 'B' in the following reaction.

\[\ce{But-1-ene ->[HBr][Peroxide] A ->[AgCN][\Delta] B}\]


Convert the following.

p-Nitrochlorobenzene to p-nitrophenol


The major product formed when 2-bromobutane is treated with alcoholic KOH is ______.


With which halogen the reactions, of alkanes are explosive?


The compound that reacts the fastest with sodium methoxide is ______.


Complete the following reaction giving major products.

\[\begin{array}{cc}
\ce{CH3}\phantom{.......}\\
|\phantom{.........}\\
\ce{CH3 - c - CH2 - Cl ->[Na/dry ether]}\\
|\phantom{.........}\\
\ce{CH3}\phantom{.......}
\end{array}\]


Complete the following reaction sequences by writing the structural formulae of the organic compounds 'A', 'B' and 'C'.

\[\ce{2-Bromobutan ->[alc. KOH] A ->[][Br2] B ->[][NANH2] C}\]


Complete the following reaction, giving a major product.

\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{................}
\end{array}\]


Complete the following reaction giving major product.

\[\begin{array}{cc}
\ce{CH3}\phantom{...............}\\
|\phantom{..................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether]A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{.................}
\end{array}\]


Give a reason for the following:

Ethoxy ethane with conc. HI at 373 K gives C2H5OH and CH3I but not CH3OH and C2H5I.


Complete the following reaction giving major product.

\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl->[Na/ dry ether]A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{................}\\
\end{array}\]


Identify the substrate 'X' in the following reaction.

\[\ce{\underset{}{X + O2} ->[i) Co-naphtenate 423 K][ii) dil HClΔ] \underset{\underset{}{}}{Phenol + Acetone}}\]


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