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प्रश्न
from the following pair would undergo SN2 faster from the other?
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उत्तर
Compound (a) will undergo SN2 mechanism faster than (b).
Explanation:
- Sincey
is a primary halide it undergoes S2N reaction faster than
. - Since iodine is a better leaving group than chloride, 1-iodo propane (CH3CH2CH2I) undergoes S2N reaction faster than l-chloropropane (CH3CH2CH2CI).
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संबंधित प्रश्न
Complete the following reaction giving major products.
\[\begin{array}{cc}\ce{CH3 - CH = CH3 ->[Red P/Br2] A ->[Ag2O/H2O]B}\\|\phantom{.........................}\\
\ce{OH\phantom{.......................}}\end{array}\]
Name the reagent used to bring about the following conversion.
Ethyl bromide to ethyl isocyanide
Arrange the following in the increasing order of boiling points.
- 1-Bromopropane
- 2- Bromopropane
- 1- Bromobutane
- 1-Bromo-2-methylpropane
Distinguish between SN1 and SN2 mechanism of substitution reaction.
Convert the following:
Propene to propan-1-ol
Convert the following:
Ethanol to propane nitrile
Convert the following:
2-Chloropropane to propan-1-ol
The following will react faster by SN1 mechanism
Explain the factors affecting SN1 and SN2 mechanism.
Ethyl bromide undergoes the following reaction:
\[\ce{\underset{Ethyl bromide}{C2H5Br} + \underset{(aq.)}{KOH} ->[\Delta] \underset{Ethyl alcohol}{C2H5OH} + KBr}\]
Which of the following is a WRONG statement?
The following mechanism has been proposed for the reaction of NO2 with F2 to form NO2F:
\[\ce{NO2_{(g)} + F2_{(g)} -> NO2F_{(g)} + F_{(g)} (slow)}\]
\[\ce{F_{(g)} + NO2_{(g)} -> NO2F_{(g)} (fast)}\]
The order of the reaction with respect to NO2(g)
What type of hybridisation is present in carbocation formed during the alkaline hydrolysis of 1- bromo-1- phenyl ethane?
Which of the following is FALSE regarding SN2 reaction mechanism?
Identify major product 'B' in the following reaction.
\[\ce{But-1-ene ->[HBr][Peroxide] A ->[AgCN][\Delta] B}\]
Convert the following.
p-Nitrochlorobenzene to p-nitrophenol
The major product formed when 2-bromobutane is treated with alcoholic KOH is ______.
With which halogen the reactions, of alkanes are explosive?
The compound that reacts the fastest with sodium methoxide is ______.
Complete the following reaction giving major products.
\[\begin{array}{cc}
\ce{CH3}\phantom{.......}\\
|\phantom{.........}\\
\ce{CH3 - c - CH2 - Cl ->[Na/dry ether]}\\
|\phantom{.........}\\
\ce{CH3}\phantom{.......}
\end{array}\]
Complete the following reaction sequences by writing the structural formulae of the organic compounds 'A', 'B' and 'C'.
\[\ce{2-Bromobutan ->[alc. KOH] A ->[][Br2] B ->[][NANH2] C}\]
Complete the following reaction, giving a major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{................}
\end{array}\]
Complete the following reaction giving major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{...............}\\
|\phantom{..................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether]A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{.................}
\end{array}\]
Give a reason for the following:
Ethoxy ethane with conc. HI at 373 K gives C2H5OH and CH3I but not CH3OH and C2H5I.
Complete the following reaction giving major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl->[Na/ dry ether]A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{................}\\
\end{array}\]
Identify the substrate 'X' in the following reaction.
\[\ce{\underset{}{X + O2} ->[i) Co-naphtenate 423 K][ii) dil HClΔ] \underset{\underset{}{}}{Phenol + Acetone}}\]
