Advertisements
Advertisements
Question
Explain why p-nitrophenol is more acidic than phenol.
Advertisements
Solution
The electron-withdrawing group (−NO2), withdraws electrons and disperses the negative charge. Therefore, the −NO2 group stabilizes the phenoxide ion. Hence p-nitrophenol is more acidic than phenol.
APPEARS IN
RELATED QUESTIONS
Name the following compound according to IUPAC system.
\[\begin{array}{cc}
\phantom{........................}\ce{CH2OH}\\
\phantom{..................}|\\
\ce{CH3 - CH - CH2 - CH - CH - CH3}\\
\phantom{}|\phantom{.............}|\phantom{........}\\
\phantom{..}\ce{CH3}\phantom{..........}\ce{OH}\phantom{........}
\end{array}\]
Name the following compound according to IUPAC system.
\[\begin{array}{cc}
\ce{H2C = CH - CH - CH2 - CH2 - CH3}\\
|\phantom{..........}\\
\ce{OH}\phantom{........}
\end{array}\]
Write IUPAC name of the following compound:
\[\begin{array}{cc}
\ce{CH3 - CH - CH - CH3}\\
|\phantom{......}|\phantom{..}\\
\ce{OH}\phantom{...}\ce{OH}\phantom{}
\end{array}\]
Write IUPAC name of the following compound:
C6H5 – O – C7H15(n−)
Give IUPAC name of the following ether:
CH3OCH2CH2Cl
Give IUPAC name of the following ether:
CH3CH2CH2OCH3
Write structural formulae for 3-Methoxyhexane
3-methylphenol is called ____________.
Butane-2-ol is ____________.
Cresol has ____________.
1-Propanol and 2-propanol can be best distinguished by:
Which of the following reagents can be used to oxidise primary alcohols to aldehydes?
(i) \[\ce{CrO3}\] in anhydrous medium.
(ii) \[\ce{KMnO4}\] in acidic medium.
(iii) Pyridinium chlorochromate.
(iv) Heat in the presence of Cu at 573 K.
Write steps to carry out the conversion of phenol to aspirin.
Match the structures of the compounds given in Column I with the name of the compounds given in Column II.
| Column I | Column II | |
| (i) | ![]() |
(a) Hydroquinone |
| (ii) | ![]() |
(b) Phenetole |
| (iii) | ![]() |
(c) Catechol |
| (iv) | ![]() |
(d) o-Cresol |
| (v) | ![]() |
(e) guinone |
| (vi) | ![]() |
(f) Resorcinol |
| (g) Anisole |
Assertion: Addition reaction of water to but-1-ene in acidic medium yields butan-1-ol.
Reason: Addition of water in acidic medium proceeds through the formation of primary carbocation.
Assertion: p-nitrophenol is more acidic than phenol.
Reason: Nitro group helps in the stabilisation of the phenoxide ion by dispersal of negative charge due to resonance.
Explain why Lewis acid is not required in bromination of phenol?
Write IUPAC name of the following compound:
\[\begin{array}{cc}
\phantom{................}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3}\phantom{..}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]






