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Karnataka Board PUCPUC Science 2nd PUC Class 12

Write steps to carry out the conversion of phenol to aspirin.

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Write steps to carry out the conversion of phenol to aspirin.

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Chapter 11: Alcohols, Phenols and Ethers - Multiple Choice Questions (Type - I) [Page 160]

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NCERT Exemplar Chemistry Exemplar [English] Class 12
Chapter 11 Alcohols, Phenols and Ethers
Multiple Choice Questions (Type - I) | Q 46 | Page 160

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Write the IUPAC name of the following compound:


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CH3OCH2CH2Cl


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IUPAC name of the compound is:

\[\begin{array}{cc}
\ce{CH3-CH-OCH3}\\
|\phantom{....}\\
\ce{CH3}\phantom{..}
\end{array}\]


Give IUPAC name of the compound given below.

\[\begin{array}{cc}
\phantom{}\ce{CH3 - CH - CH2 - CH2 - CH - CH3}\phantom{.}\\
\phantom{.........}|\phantom{...................}|\phantom{...........}\\
\phantom{..}\ce{Cl}\phantom{.................}\ce{OH}\phantom{..}
\end{array}\]


Match the structures of the compounds given in Column I with the name of the compounds given in Column II.

  Column I Column II
(i) (a) Hydroquinone
(ii) (b) Phenetole
(iii) (c) Catechol
(iv) (d) o-Cresol
(v) (e) guinone
(vi) (f) Resorcinol
    (g) Anisole

Match the starting materials given in Column I with the products formed by these (Column II) in the reaction with HI.

  Column I   Column II
(i) CH3—O—CH3 (a)
(ii) \[\begin{array}{cc}
\ce{CH3}\phantom{..................}\\
\backslash\phantom{.............}\\
\ce{CH-O-CH3}\\
/\phantom{..............}\\
\ce{CH3}\phantom{..................}
\end{array}\]
(b) \[\begin{array}{cc}
\ce{CH3}\phantom{....}\\
|\phantom{.......}\\
\ce{CH3-C-I + CH3OH}\\
|\phantom{.......}\\
\ce{CH3}\phantom{....}
\end{array}\]
(iii) \[\begin{array}{cc}
\ce{CH3}\phantom{.}\\
|\phantom{....}\\
\ce{H3C-C-O-CH3}\\
|\phantom{....}\\
\ce{CH3}\phantom{..}
\end{array}\]
(c)
(iv) (d) CH3—OH + CH3—I
    (e) \[\begin{array}{cc}
\ce{CH3}\phantom{.....................}\\
\backslash\phantom{.................}\\
\ce{CH-OH + CH3I}\\
/\phantom{.................}\\
\ce{CH3}\phantom{.....................}
\end{array}\]
    (f) \[\begin{array}{cc}
\ce{CH3}\phantom{.....................}\\
\backslash\phantom{.................}\\
\ce{CH-I + CH3OH}\\
/\phantom{.................}\\
\ce{CH3}\phantom{.....................}
\end{array}\]
    (g) \[\begin{array}{cc}
\ce{CH3}\phantom{....}\\
|\phantom{.......}\\
\ce{CH3-C-OH + CH3I}\\
|\phantom{.......}\\
\ce{CH3}\phantom{....}
\end{array}\]

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Reason: Addition of water in acidic medium proceeds through the formation of primary carbocation.


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Reason: Nitro group helps in the stabilisation of the phenoxide ion by dispersal of negative charge due to resonance.


Assertion: Phenol forms 2, 4, 6 – tribromophenol on treatment with \[\ce{Br2}\] in carbon disulphide at 273 K.

Reason: Bromine polarises in carbon disulphide.


Identify A and B in the following:


Write IUPAC names of the following compounds: 

\[\begin{array}{cc}
\phantom{...............}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3\phantom{...}OH\phantom{...}CH3}\\
\end{array}\] 


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