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Question
Draw a formula for the first five members of the homologous series beginning with the given compound.
CH3COCH3
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Solution
The first five members of each homologous series beginning with the given compounds are
CH3COCH3 : Propanone
CH3COCH2CH3 : Butanone
CH3COCH2CH2CH3 : Pentan-2-one
CH3COCH2CH2CH2CH3 : Hexan-2-one
CH3COCH2CH2CH2CH2CH3 : Heptan-2-one
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\[\begin{array}{cc}
\ce{CH3}\phantom{..................}\\
|\phantom{....................}\\
\ce{CH3 - C - CH - CH2 - CH2 - CH3}\\
|\phantom{....}|\phantom{................}\\
\ce{CH3} \ce{CH3}\phantom{..............}
\end{array}\]
Identify primary, secondary, tertiary and quaternary carbon in the following compound.
\[\begin{array}{cc}
\ce{CH3}\phantom{..................}\\
|\phantom{....................}\\
\ce{CH3 - C - CH - CH2 - CH2 - CH3}\\
|\phantom{....}|\phantom{................}\\
\ce{CH3}\phantom{..}\ce{CH3}\phantom{..............}\\
\end{array}\]
Identify primary, secondary, tertiary, and quaternary carbons in the following compound.
\[\begin{array}{cc}
\ce{CH3\phantom{.................}}\\
|\phantom{....................}\\
\ce{CH3 - C - CH - CH2 - CH2 - CH3}\\
|\phantom{....}|\phantom{................}\\
\ce{CH3 CH3\phantom{.............}}
\end{array}\]
Identify the α - carbons in the following species and give the total number of α-hydrogen in each.
\[\ce{CH3 - CH2 - \overset{\oplus}{C}H - CH2 - CH3}\]
Indicate the σ and π bonds in the following molecule:
\[\ce{HCONHCH3}\]
Identify primary, secondary, tertiary and quaternary carbon in the following compound:
\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{....................}\\
\ce{CH3 - C - CH - CH2 - CH2 - CH3}\\
|\phantom{....}|\phantom{................}\\
\ce{CH3}\phantom{.}\ce{CH3}\phantom{..............}\\
\end{array}\]
Identify primary, secondary, tertiary and quaternary carbon in the following compound.
\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{....................}\\
\ce{CH3 - C - CH - CH2 - CH2 - CH3}\\
|\phantom{.....}|\phantom{................}\\
\ce{CH3}\phantom{.}\ce{CH3}\phantom{..............}
\end{array}\]
Identify primary, secondary, tertiary and quaternary carbon in the following compound.
\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{....................}\\
\ce{CH3 - C - CH - CH2 - CH2 - CH3}\\
|\phantom{....}|\phantom{................}\\
\ce{CH3}\phantom{.}\ce{CH3}\phantom{..............}
\end{array}\]
