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प्रश्न
Describe the general trends in the following properties of the elements in Groups 13 and 14.
Atomic size
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उत्तर
Grp-13 The atomic size of the boron family follows the irregular trend. Generally, down the group the size increases but Gallium has a smaller atomic radius than Aluminium due to the poor shielding effect of 3d-orbitals.
Order: B < Ga < Al < In < Ti
Grp-14 The size of the carbon family is smaller than the modern family and as we move down the group the atomic size increases regularly. The increase in covalent radius from carbon to silicon is prominent while from Silicon to lead a small increase in covalent radius is observed; this is due to the presence of completely filled D and f-orbital in the heavier members.
Order: C < Si < Ge < Sn < Pb
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संबंधित प्रश्न
How can you explain higher stability of BCl3 as compared to TlCl3?
Write a balanced equation for B2H6 + NH3 → ?
Which of the following oxides is acidic in nature?
A compound X, of boron reacts with NH3 on heating to give another compound Y which is called inorganic benzene. The compound X can be prepared by treating BF3 with Lithium aluminium hydride. The compounds X and Y are represented by the formulas.
Dry ice is ______.
Which of the following statements are correct. Answer on the basis of Figure.
(i) The two birdged hydrogen atoms and the two boron atoms lie in one plane;
(ii) Out of six B – H bonds two bonds can be described in terms of 3 centre 2-electron bonds.
(iii) Out of six B – H bonds four B – H bonds can be described in terms of 3 centre 2 electron bonds;
(iv) The four-terminal B – H bonds are two centre-two electron regular bonds.
Explain why the following compounds behave as Lewis acids?
AlCl3
Aluminium dissolves in mineral acids and aqueous alkalies and thus shows amphoteric character. A piece of aluminium foil is treated with dilute hydrochloric acid or dilute sodium hydroxide solution in a test tube and on bringing a burning matchstick near the mouth of the test tube, a pop sound indicates the evolution of hydrogen gas. The same activity when performed with concentrated nitric acid, reaction doesn’t proceed. Explain the reason.
Explain the following:
Boron does not exist as B3+ ion.
Explain the following:
PbX2 is more stable than PbX4.
Explain the following:
Tl (NO3)3 acts as an oxidising agent.
Match the species given in Column I with properties given in Column II.
| Column I | Column II |
| (i) Diborane | (a) Used as a flux for soldering metals |
| (ii) Galluim | (b) Crystalline form of silica |
| (iii) Borax | (c) Banana bonds |
| (iv) Aluminosilicate | (d) Low melting, high boiling, useful for measuring high temperatures |
| (v) Quartz | (e) Used as catalyst in petrochemical industries |
Describe the general trends in the following properties of the elements in Groups 13 and 14.
Metallic character
Account for the following observations:
Though fluorine is more electronegative than chlorine yet BF3 is a weaker Lewis acid than BCl3
Account for the following observations:
The +1 oxidation state of thallium is more stable than its +3 state.
Three pairs of compounds are given below. Identify that compound in each of the pairs which has group 13 element in more stable oxidation state. Give reason for your choice. State the nature of bonding also.
TlCl3, TlCl
BCl3 exists as monomer whereas AlCl3 is dimerised through halogen bridging. Give reason. Explain the structure of the dimer of AlCl3 also.
Boron fluoride exists as BF3 but boron hydride doesn’t exist as BH3. Give reason. In which form does it exist? Explain its structure.
