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प्रश्न
Identify the compounds A, X and Z in the following reactions:
\[\ce{A + 2HCl + 5H2O -> 2NaCl + X}\]
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उत्तर
\[\ce{\underset{\underset{(Borax)}{(A)}}{Na2B4O7} + 2HCl + 5H2O -> 2NaCl + \underset{\underset{(Boric acid)}{(X)}}{4H3BO3}}\]
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संबंधित प्रश्न
How can you explain higher stability of BCl3 as compared to TlCl3?
If B–Cl bond has a dipole moment, explain why BCl3 molecule has zero dipole moment.
The exhibition of highest co-ordination number depends on the availability of vacant orbitals in the central atom. Which of the following elements is not likely to act as central atom in \[\ce{MF^{3-}6}\]?
A compound X, of boron reacts with NH3 on heating to give another compound Y which is called inorganic benzene. The compound X can be prepared by treating BF3 with Lithium aluminium hydride. The compounds X and Y are represented by the formulas.
Which of the following statements are correct. Answer on the basis of Figure.

(i) The two birdged hydrogen atoms and the two boron atoms lie in one plane;
(ii) Out of six B – H bonds two bonds can be described in terms of 3 centre 2-electron bonds.
(iii) Out of six B – H bonds four B – H bonds can be described in terms of 3 centre 2 electron bonds;
(iv) The four-terminal B – H bonds are two centre-two electron regular bonds.
Explain the following:
Boron does not exist as B3+ ion.
Explain the following:
PbX2 is more stable than PbX4.
Explain the following:
Pb4+ acts as an oxidising agent but Sn2+ acts as a reducing agent.
Explain the following:
Electron gain enthalpy of chlorine is more negative as compared to fluorine.
Identify the compounds A, X and Z in the following reactions:
\[\ce{X ->[Δ][370 K] HBO2 ->[Δ][> 370 K] Z}\]
Describe the general trends in the following properties of the elements in Groups 13 and 14.
Metallic character
Account for the following observations:
Though fluorine is more electronegative than chlorine yet BF3 is a weaker Lewis acid than BCl3
Account for the following observations:
The +1 oxidation state of thallium is more stable than its +3 state.
Three pairs of compounds are given below. Identify that compound in each of the pairs which has group 13 element in more stable oxidation state. Give reason for your choice. State the nature of bonding also.
TlCl3, TlCl
Boron fluoride exists as BF3 but boron hydride doesn’t exist as BH3. Give reason. In which form does it exist? Explain its structure.
