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Explain why the following compounds behave as Lewis acids? AlCl3

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प्रश्न

Explain why the following compounds behave as Lewis acids?

AlCl3

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उत्तर

AlCl3 forms a covalent bond with chlorine by forming three single bonds of chlorine as aluminium has three electrons in its valence shell and act as an electron-deficient compound and act as lewis acid.

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पाठ 11: The p-block Elements - Multiple Choice Questions (Type - I) [पृष्ठ १३८]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 11
पाठ 11 The p-block Elements
Multiple Choice Questions (Type - I) | Q 25.(ii) | पृष्ठ १३८

संबंधित प्रश्‍न

How can you explain higher stability of BClas compared to TlCl3?


Aluminium trifluoride is insoluble in anhydrous HF but dissolves on the addition of NaF. Aluminium trifluoride precipitates out of the resulting solution when gaseous BF3 is bubbled through. Give reasons.


What happens when BF3 is reacted with ammonia?


In some of the reactions thallium resembles aluminium, whereas in others it resembles with group I metals. Support this statement by giving some evidences.


The geometry of a complex species can be understood from the knowledge of type of hybridisation of orbitals of central atom. The hybridisation of orbitals of central atom in [Be(OH)4] and the geometry of the complex are respectively.


Which of the following oxides is acidic in nature?


Which of the following statements are correct. Answer on the basis of Figure.

(i) The two birdged hydrogen atoms and the two boron atoms lie in one plane;

(ii) Out of six B – H bonds two bonds can be described in terms of 3 centre 2-electron bonds.

(iii) Out of six B – H bonds four B – H bonds can be described in terms of 3 centre 2 electron bonds;

(iv) The four-terminal B – H bonds are two centre-two electron regular bonds.


Aluminium dissolves in mineral acids and aqueous alkalies and thus shows amphoteric character. A piece of aluminium foil is treated with dilute hydrochloric acid or dilute sodium hydroxide solution in a test tube and on bringing a burning matchstick near the mouth of the test tube, a pop sound indicates the evolution of hydrogen gas. The same activity when performed with concentrated nitric acid, reaction doesn’t proceed. Explain the reason.


Explain the following:

Electron gain enthalpy of chlorine is more negative as compared to fluorine.


Explain the following:

Tl (NO3)3 acts as an oxidising agent.


Identify the compounds A, X and Z in the following reactions:

\[\ce{X ->[Δ][370 K] HBO2 ->[Δ][> 370 K] Z}\]


Complete the following chemical equations:

\[\ce{Z + 3 LiAlH4 -> X + 3LiF + 3AlF_3}\]

\[\ce{X + 6H2 -> Y + 6H2}\]

\[\ce{3X + 3O2 ->[Δ] B2O3 + 3H2O}\]


Match the species given in Column I with properties given in Column II.

Column I Column II
(i) Diborane (a) Used as a flux for soldering metals
(ii) Galluim (b) Crystalline form of silica
(iii) Borax (c) Banana bonds
(iv) Aluminosilicate (d) Low melting, high boiling, useful for measuring high temperatures
(v) Quartz (e) Used as catalyst in petrochemical industries

Account for the following observations:

Though fluorine is more electronegative than chlorine yet BF3 is a weaker Lewis acid than BCl3 


Three pairs of compounds are given below. Identify that compound in each of the pairs which has group 13 element in more stable oxidation state. Give reason for your choice. State the nature of bonding also.

InCl3, InCl


Boron fluoride exists as BF3 but boron hydride doesn’t exist as BH3. Give reason. In which form does it exist? Explain its structure.


Boron compounds behave as Lewis acids because of their ______.


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