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Explain the following: Electron gain enthalpy of chlorine is more negative as compared to fluorine. - Chemistry

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प्रश्न

Explain the following:

Electron gain enthalpy of chlorine is more negative as compared to fluorine.

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उत्तर

Due to small size, the electron-electron repulsions in the relatively compact 2p-subshell of F are quite strong and hence the incoming electron is not accepted with the same ease as in case of bigger Cl atom where repulsions are comparatively weak. Thus, electron gain enthalpy of chlorine is more negative as compared to that of fluorine.

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Group 13 Elements - The Boron Family
  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
पाठ 11: The p-block Elements - Multiple Choice Questions (Type - I) [पृष्ठ १३८]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 11
पाठ 11 The p-block Elements
Multiple Choice Questions (Type - I) | Q 33.(vi) | पृष्ठ १३८

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How can you explain higher stability of BClas compared to TlCl3?


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Explain why the following compounds behave as Lewis acids?

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\[\ce{X ->[Δ][370 K] HBO2 ->[Δ][> 370 K] Z}\]


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\[\ce{Z + 3 LiAlH4 -> X + 3LiF + 3AlF_3}\]

\[\ce{X + 6H2 -> Y + 6H2}\]

\[\ce{3X + 3O2 ->[Δ] B2O3 + 3H2O}\]


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Column I Column II
(i) Diborane (a) Used as a flux for soldering metals
(ii) Galluim (b) Crystalline form of silica
(iii) Borax (c) Banana bonds
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(v) Quartz (e) Used as catalyst in petrochemical industries

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Column I Column II
(i) Boron in [B(OH)4] (a) sp2
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(iii) Boron in B2H6 (c) sp3d2
(iv) Carbon in Buckminsterfullerene  
(v) Silicon in \[\ce{SiO^{4-}4}\]  
(vi) Germanium in [GeCl6]2–  

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Ionisation enthalpy


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