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Describe the general trends in the following properties of the elements in Groups 13 and 14. Metallic character

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प्रश्न

Describe the general trends in the following properties of the elements in Groups 13 and 14.

Metallic character

दीर्घउत्तर
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उत्तर

The metallic character in group 13 follows an unusual trend. Metallic character First increases from Boron to aluminium and then decreases from aluminium to thallium. This decrease is majorly due to the poor shielding effect of d and f electrons present in the heavier metals.

In group-14, as we move down the group, the metallic character increases.

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पाठ 11: The p-block Elements - Multiple Choice Questions (Type - I) [पृष्ठ १४०]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 11
पाठ 11 The p-block Elements
Multiple Choice Questions (Type - I) | Q 41.(iii) | पृष्ठ १४०

संबंधित प्रश्‍न

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How would you explain the lower atomic radius of Ga as compared to Al?


What do you understand by inert pair effect?


Which of the following oxides is acidic in nature?


Ionisation enthalpy (∆iH1kJ mol–1) for the elements of Group 13 follows the order.


Cement, the important building material is a mixture of oxides of several elements. Besides calcium, iron and sulphur, oxides of elements of which of the group (s) are present in the mixture?


Explain the following:

Boron does not exist as B3+ ion.


Explain the following:

Tl (NO3)3 acts as an oxidising agent.


Match the species given in Column I with the properties mentioned in Column II.

Column I Column II
(i) \[\ce{BF^{-}4}\] (a) Oxidation state of central atom is +4
(ii) AICI3 (b) Strong oxidising agent
(iii) SnO (c) Lewis acid
(iv) PbO2 (d) Can be further oxidised
  (e) Tetrahedral shape

Describe the general trends in the following properties of the elements in Groups 13 and 14.

Atomic size


Describe the general trends in the following properties of the elements in Groups 13 and 14.

Oxidation states


Account for the following observations:

PbO2 is a stronger oxidising agent than SnO2 


Boron fluoride exists as BF3 but boron hydride doesn’t exist as BH3. Give reason. In which form does it exist? Explain its structure.


A nonmetallic element of group 13, used in making bullet proof vests is extremely hard solid of black colour. It can exist in many allotropic forms and has unusually high melting point. Its trifluoride acts as Lewis acid towards ammonia. The element exihibits maximum covalency of four. Identify the element and write the reaction of its trifluoride with ammonia. Explain why does the trifluoride act as a Lewis acid.


Boron compounds behave as Lewis acids because of their ______.


Taking stability as the factor, which one of the following represents the correct relationship?


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