English
Karnataka Board PUCPUC Science Class 11

Describe the general trends in the following properties of the elements in Groups 13 and 14. Metallic character

Advertisements
Advertisements

Question

Describe the general trends in the following properties of the elements in Groups 13 and 14.

Metallic character

Long Answer
Advertisements

Solution

The metallic character in group 13 follows an unusual trend. Metallic character First increases from Boron to aluminium and then decreases from aluminium to thallium. This decrease is majorly due to the poor shielding effect of d and f electrons present in the heavier metals.

In group-14, as we move down the group, the metallic character increases.

shaalaa.com
  Is there an error in this question or solution?
Chapter 11: The p-block Elements - Multiple Choice Questions (Type - I) [Page 140]

APPEARS IN

NCERT Exemplar Chemistry Exemplar [English] Class 11
Chapter 11 The p-block Elements
Multiple Choice Questions (Type - I) | Q 41.(iii) | Page 140

RELATED QUESTIONS

How can you explain higher stability of BClas compared to TlCl3?


How would you explain the lower atomic radius of Ga as compared to Al?


Ionisation enthalpy (∆iH1kJ mol–1) for the elements of Group 13 follows the order.


The most commonly used reducing agent is ______.


Dry ice is ______.


Which of the following statements are correct. Answer on the basis of Figure.

(i) The two birdged hydrogen atoms and the two boron atoms lie in one plane;

(ii) Out of six B – H bonds two bonds can be described in terms of 3 centre 2-electron bonds.

(iii) Out of six B – H bonds four B – H bonds can be described in terms of 3 centre 2 electron bonds;

(iv) The four-terminal B – H bonds are two centre-two electron regular bonds.


When BCl3 is treated with water, it hydrolyses and forms [B[OH]4] only whereas AlCl3 in acidified aqueous solution forms [Al(H2O)6]3+ ion. Explain what is the hybridisation of boron and aluminium in these species?


Aluminium dissolves in mineral acids and aqueous alkalies and thus shows amphoteric character. A piece of aluminium foil is treated with dilute hydrochloric acid or dilute sodium hydroxide solution in a test tube and on bringing a burning matchstick near the mouth of the test tube, a pop sound indicates the evolution of hydrogen gas. The same activity when performed with concentrated nitric acid, reaction doesn’t proceed. Explain the reason.


Explain the following:

PbX2 is more stable than PbX4.


Identify the compounds A, X and Z in the following reactions:

\[\ce{A + 2HCl + 5H2O -> 2NaCl + X}\]


Describe the general trends in the following properties of the elements in Groups 13 and 14.

Ionisation enthalpy


Describe the general trends in the following properties of the elements in Groups 13 and 14.

Oxidation states


Describe the general trends in the following properties of the elements in Groups 13 and 14.

Nature of halides


Account for the following observations:

Though fluorine is more electronegative than chlorine yet BF3 is a weaker Lewis acid than BCl3 


Account for the following observations:

PbO2 is a stronger oxidising agent than SnO2 


Account for the following observations:

The +1 oxidation state of thallium is more stable than its +3 state.


Three pairs of compounds are given below. Identify that compound in each of the pairs which has group 13 element in more stable oxidation state. Give reason for your choice. State the nature of bonding also.

AlCl3 , AlCl


Taking stability as the factor, which one of the following represents the correct relationship?


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×