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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Write the mechanism of acid-catalysed dehydration of ethanol to yield ethene.

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प्रश्न

Write the mechanism of acid-catalysed dehydration of ethanol to yield ethene.

रासायनिक समीकरण/संरचनाएँ
लघु उत्तरीय
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उत्तर

In the presence of conc. acids such as H3PO4 and H2SO4 alcohols undergo dehydration to yield alkenes.

\[\ce{\underset{Ethanol}{H3C - CH2 - OH} ->[conc{.} H+/Delta] \underset{Ethene}{CH2 = CH2} + H2O}\]

The mechanism for this reaction is:

Protonation of ethanol (Step 1):

Formation of carbocation (Step 2):

Formation of ethene and regeneration of proton (Step 3):

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अध्याय 7: Alcohols, Phenols and Ethers - Exercises [पृष्ठ २२३]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
अध्याय 7 Alcohols, Phenols and Ethers
Exercises | Q 7.19 | पृष्ठ २२३

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\[\begin{array}{cc}
\phantom{...................................}\ce{Br}\\
\phantom{..................................}|\\
\ce{CH3 - CH - CH - CH3 ->[HBr] CH3 - C - CH2 - CH3}\\
|\phantom{.........}|\phantom{...................................}|\phantom{...........}\\
\ce{CH3}\phantom{...}\ce{OH}\phantom{...............................}\ce{CH3}\phantom{.......}\\
\end{array}\]

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Write the mechanism of acid-catalysed dehydration of ethanol to yield ethene.


Write the mechanism of acid dehydration of ethanol to yield ethene.


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