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प्रश्न
In Kolbe’s reaction, instead of phenol, phenoxide ion is treated with carbon dioxide. Why?
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उत्तर
Phenoxide ion is more reactive than phenol towards electrophilic substitution. The negative charge on oxygen is transferred to benzene through resonance. This helps in the attachment of CO2 which is a weak electrophile to the benzene ring finally giving salicylic acid.
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संबंधित प्रश्न
Write the mechanism of the following reaction:

Write the mechanism of the following reaction :

Ortho and para nitrophenols are more acidic than phenol. Draw the resonance structures of the corresponding phenoxide ions.
Write the mechanism of acid-catalysed dehydration of ethanol to yield ethene.
Name the reagent used in the following reaction:
Benzyl alcohol to benzoic acid.
Write the mechanism (using curved arrow notation) of the following reaction :

By which of the following methods alcohol can be prepared in excellent yield?
Which of the following are used to convert RCHO into RCH2OH?
(i) H2/Pd
(ii) LiAlH4
(iii) NaBH4
(iv) Reaction with RMgX followed by hydrolysis
During dehydration of alcohols to alkenes by heating with cone. H2SO4 the initial step is ____________.
\[\ce{CH3CH2OH}\] can be converted into \[\ce{CH3CHO}\] by ______.
Suggest a reagent for the following conversion.

Why is the C – O – H bond angle in alcohols slightly less than the tetrahedral angle whereas the C – O – C bond angle in ether is slightly greater?
What happens when (CH3)3 C – OH is heated with Cu/573 K?
Write the chemical equation in support of your answer.
Write the mechanism of acid dehydration of ethanol to yield ethene.
Write the mechanism of acid-catalysed dehydration of ethanol to yield ethene.
Write the mechanism of acid dehydration of ethanol to yield ethene.
Write the mechanism of acid dehydration of ethanol to yield ethene.
Write the mechanism of acid dehydration of ethanol to yield ethene.
