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Dipole moment of phenol is smaller than that of methanol. Why?

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प्रश्न

Dipole moment of phenol is smaller than that of methanol. Why?

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उत्तर

In phenol, C – O bond is less polar due to electron-withdrawing effect of benzene ring, whereas in methanol C – O bond is more polar due to electron releasing effect of –CH3 group. Hence, the dipole moment of phenol (1.54 D) is smaller than that of methanol (1.71 D).

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अध्याय 11: Alcohols, Phenols and Ethers - Multiple Choice Questions (Type - I) [पृष्ठ १६०]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
अध्याय 11 Alcohols, Phenols and Ethers
Multiple Choice Questions (Type - I) | Q 49 | पृष्ठ १६०

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\[\begin{array}{cc}
\phantom{.}\ce{CH3 - CH - CH - CH - CH - CH3}\phantom{}\\
\phantom{......}|\phantom{......}|\phantom{......}|\phantom{.....}|\phantom{........}\\
\phantom{...}\ce{CH3}\phantom{...}\ce{OH}\phantom{...}\ce{C2H5}\phantom{.}\ce{OH}\phantom{...}\end{array}\]


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