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Dipole moment of phenol is smaller than that of methanol. Why?

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प्रश्न

Dipole moment of phenol is smaller than that of methanol. Why?

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उत्तर

In phenol, C – O bond is less polar due to electron-withdrawing effect of benzene ring, whereas in methanol C – O bond is more polar due to electron releasing effect of –CH3 group. Hence, the dipole moment of phenol (1.54 D) is smaller than that of methanol (1.71 D).

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अध्याय 11: Alcohols, Phenols and Ethers - Multiple Choice Questions (Type - I) [पृष्ठ १६०]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
अध्याय 11 Alcohols, Phenols and Ethers
Multiple Choice Questions (Type - I) | Q 49 | पृष्ठ १६०

संबंधित प्रश्न

Write resonance structures of aniline. What is the action of benzene diazonium chloride on ethanol? 


How do you convert the following:

Ethanol to Propan-2-ol


Methanol and ethanol are miscible in water due to ____________.


If ethanol dissolves in water, then which of the following would be observed:


Write the IUPAC name of the following compound.

\[\begin{array}{cc}
\phantom{.}\ce{CH3 - CH - CH - CH - CH - CH3}\phantom{}\\
\phantom{......}|\phantom{......}|\phantom{......}|\phantom{.....}|\phantom{........}\\
\phantom{...}\ce{CH3}\phantom{...}\ce{OH}\phantom{...}\ce{C2H5}\phantom{.}\ce{OH}\phantom{...}\end{array}\]


Suggest a reagent for conversion of ethanol to ethanal.


Suggest a reagent for conversion of ethanol to ethanoic acid.


Arrange the following compounds in increasing order of acidity and give a suitable explanation.

Phenol, o-nitrophenol, o-cresol


The carbon-oxygen bond in phenol is slightly stronger than that in methanol. Why?


Arrange water, ethanol and phenol in increasing order of acidity and give reason for your answer.


Match the items of column I with items of column II.

  Column I Column II
(i) Methanol (a) Conversion of phenol to o-hydroxysalicylic acid
(ii) Kolbe’s reaction (b) Ethyl alcohol
(iii) Williamson’s synthesis (c) Conversion of phenol to salicylaldehyde
(iv) Conversion of 2° alcohol to ketone (d) Wood spirit
(v) Reimer-Tiemann reaction (e) Heated copper at 573 K
(vi) Fermentation (f) Reaction of alkyl halide with sodium alkoxide

Assertion: Ethanol is a weaker acid than phenol.

Reason: Sodium ethoxide may be prepared by the reaction of ethanol with aqueous \[\ce{NaOH}\].


Alcoholic fermentation is brought about by the action of


Write chemical reactions of following reagents on methoxyethane:

dilute H2SO4


If the starting material is 1-methyl-1,2-epoxy cyclopentane, of absolute configuration, decide which one compound correctly represents the product of its reaction with sodium methoxide in methanol.


Convert the following Ethanal to ethanol.


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