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प्रश्न
Phenol can be distinguished from ethanol by the reactions with:
(i) \[\ce{Br2/water}\]
(ii) \[\ce{Na}\]
(iii) Neutral \[\ce{FeCl3}\]
(iv) All the above
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उत्तर
(i) \[\ce{Br2/water}\]
(iii) Neutral \[\ce{FeCl3}\]
Explanation:
Ethanol does not give any reaction with neutral \[\ce{FeCl3}\] solution while phenol gives violet colour-neutral \[\ce{FeCl3}\]. When phenol is treated with bromine water, 2, 4, 6-tribromophenol is formed as white precipitate. Ethanol does not react with bromine water.
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संबंधित प्रश्न
Among the following the one which reacts most readily with ethanol is:
Methanol and ethanol are miscible in water due to ____________.
If ethanol dissolves in water, then which of the following would be observed:
Wood spirit is known as acetone:
Phenol is less acidic than ______.
What is denatured alcohol?
Out of 2-chloroethanol and ethanol which is more acidic and why?
Suggest a reagent for conversion of ethanol to ethanal.
Name the enzymes and write the reactions involved in the preparation of ethanol from sucrose by fermentation.
The carbon-oxygen bond in phenol is slightly stronger than that in methanol. Why?
Arrange water, ethanol and phenol in increasing order of acidity and give reason for your answer.
Match the items of column I with items of column II.
| Column I | Column II | |
| (i) | Antifreeze used in car engine | (a) Neutral ferric chloride |
| (ii) | Solvent used in perfumes | (b) Glycerol |
| (iii) | Starting material for picric acid | (c) Methanol |
| (iv) | Wood spirit | (d) Phenol |
| (v) | Reagent used for detection of phenolic group | (e) Ethleneglycol |
| (vi) | By product of soap industry used in cosmetics | (f) Ethanol |
Match the items of column I with items of column II.
| Column I | Column II | |
| (i) | Methanol | (a) Conversion of phenol to o-hydroxysalicylic acid |
| (ii) | Kolbe’s reaction | (b) Ethyl alcohol |
| (iii) | Williamson’s synthesis | (c) Conversion of phenol to salicylaldehyde |
| (iv) | Conversion of 2° alcohol to ketone | (d) Wood spirit |
| (v) | Reimer-Tiemann reaction | (e) Heated copper at 573 K |
| (vi) | Fermentation | (f) Reaction of alkyl halide with sodium alkoxide |
Convert the following:
Propanenitrile to ethanol.
Which of the following is known as wood spirit?
Convert the following Ethanal to ethanol.
How methanol is obtained from methanal.
