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प्रश्न
Give simple chemical test to distinguish between Ethanol and Phenol.
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उत्तर
Phenol is unsaturated aromatic alcohol, while ethanol is saturated aliphatic alcohol.
Ethanol reacts with triiodomethane (iodoform test) and forms the yellow precipitate, while phenol does not give this test.
Phenol has benzene ring, it undergoes diazo coupling reaction, while ethanol does not give this test.
Phenol decolorises bromine solution showing it is an unsaturated compound while ethanol does not decolorize bromine solution showing it is a saturated compound.
With neutral FeCl3, phenol forms violet complex while ethanol does not.
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संबंधित प्रश्न
How do you convert the following:
Ethanol to Propan-2-ol
Write the mechanism of the following reaction :
\[\ce{C2H5OH->[H2SO4][443K]CH2=CH2 + H2O}\]
Phenol can be distinguished from ethanol by the reactions with:
(i) \[\ce{Br2/water}\]
(ii) \[\ce{Na}\]
(iii) Neutral \[\ce{FeCl3}\]
(iv) All the above
Suggest a reagent for conversion of ethanol to ethanal.
Suggest a reagent for conversion of ethanol to ethanoic acid.
Arrange water, ethanol and phenol in increasing order of acidity and give reason for your answer.
Match the items of column I with items of column II.
| Column I | Column II | |
| (i) | Antifreeze used in car engine | (a) Neutral ferric chloride |
| (ii) | Solvent used in perfumes | (b) Glycerol |
| (iii) | Starting material for picric acid | (c) Methanol |
| (iv) | Wood spirit | (d) Phenol |
| (v) | Reagent used for detection of phenolic group | (e) Ethleneglycol |
| (vi) | By product of soap industry used in cosmetics | (f) Ethanol |
Convert the following:
Propanenitrile to ethanol.
Write chemical reactions of following reagents on methoxyethane:
dilute H2SO4
If the starting material is 1-methyl-1,2-epoxy cyclopentane, of absolute configuration, decide which one compound correctly represents the product of its reaction with sodium methoxide in methanol.
