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प्रश्न
Give simple chemical test to distinguish between Ethanol and Phenol.
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उत्तर
Phenol is unsaturated aromatic alcohol, while ethanol is saturated aliphatic alcohol.
Ethanol reacts with triiodomethane (iodoform test) and forms the yellow precipitate, while phenol does not give this test.
Phenol has benzene ring, it undergoes diazo coupling reaction, while ethanol does not give this test.
Phenol decolorises bromine solution showing it is an unsaturated compound while ethanol does not decolorize bromine solution showing it is a saturated compound.
With neutral FeCl3, phenol forms violet complex while ethanol does not.
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संबंधित प्रश्न
Write the mechanism of the following reaction :
\[\ce{C2H5OH->[H2SO4][443K]CH2=CH2 + H2O}\]
Phenol is less acidic than ______.
Phenol can be distinguished from ethanol by the reactions with:
(i) \[\ce{Br2/water}\]
(ii) \[\ce{Na}\]
(iii) Neutral \[\ce{FeCl3}\]
(iv) All the above
Write the IUPAC name of the following compound.
\[\begin{array}{cc}
\phantom{.}\ce{CH3 - CH - CH - CH - CH - CH3}\phantom{}\\
\phantom{......}|\phantom{......}|\phantom{......}|\phantom{.....}|\phantom{........}\\
\phantom{...}\ce{CH3}\phantom{...}\ce{OH}\phantom{...}\ce{C2H5}\phantom{.}\ce{OH}\phantom{...}\end{array}\]
Suggest a reagent for conversion of ethanol to ethanal.
Match the items of column I with items of column II.
| Column I | Column II | |
| (i) | Methanol | (a) Conversion of phenol to o-hydroxysalicylic acid |
| (ii) | Kolbe’s reaction | (b) Ethyl alcohol |
| (iii) | Williamson’s synthesis | (c) Conversion of phenol to salicylaldehyde |
| (iv) | Conversion of 2° alcohol to ketone | (d) Wood spirit |
| (v) | Reimer-Tiemann reaction | (e) Heated copper at 573 K |
| (vi) | Fermentation | (f) Reaction of alkyl halide with sodium alkoxide |
Assertion: Ethanol is a weaker acid than phenol.
Reason: Sodium ethoxide may be prepared by the reaction of ethanol with aqueous \[\ce{NaOH}\].
Tonics in general contain
Liquor poisoning is due to
3, 3-dimethyl-1-butene was subject to following reactions:
