Advertisements
Advertisements
प्रश्न
Dipole moment of phenol is smaller than that of methanol. Why?
Advertisements
उत्तर
In phenol, C – O bond is less polar due to electron-withdrawing effect of benzene ring, whereas in methanol C – O bond is more polar due to electron releasing effect of –CH3 group. Hence, the dipole moment of phenol (1.54 D) is smaller than that of methanol (1.71 D).
APPEARS IN
संबंधित प्रश्न
How do you convert the following:
Ethanol to Propan-2-ol
Give simple chemical test to distinguish between Ethanol and Phenol.
If ethanol dissolves in water, then which of the following would be observed:
Phenol is less acidic than ______.
Phenol can be distinguished from ethanol by the reactions with:
(i) \[\ce{Br2/water}\]
(ii) \[\ce{Na}\]
(iii) Neutral \[\ce{FeCl3}\]
(iv) All the above
Write the IUPAC name of the following compound.
\[\begin{array}{cc}
\phantom{.}\ce{CH3 - CH - CH - CH - CH - CH3}\phantom{}\\
\phantom{......}|\phantom{......}|\phantom{......}|\phantom{.....}|\phantom{........}\\
\phantom{...}\ce{CH3}\phantom{...}\ce{OH}\phantom{...}\ce{C2H5}\phantom{.}\ce{OH}\phantom{...}\end{array}\]
Out of 2-chloroethanol and ethanol which is more acidic and why?
Suggest a reagent for conversion of ethanol to ethanal.
Arrange the following compounds in increasing order of acidity and give a suitable explanation.
Phenol, o-nitrophenol, o-cresol
Name the enzymes and write the reactions involved in the preparation of ethanol from sucrose by fermentation.
Arrange water, ethanol and phenol in increasing order of acidity and give reason for your answer.
Match the items of column I with items of column II.
| Column I | Column II | |
| (i) | Antifreeze used in car engine | (a) Neutral ferric chloride |
| (ii) | Solvent used in perfumes | (b) Glycerol |
| (iii) | Starting material for picric acid | (c) Methanol |
| (iv) | Wood spirit | (d) Phenol |
| (v) | Reagent used for detection of phenolic group | (e) Ethleneglycol |
| (vi) | By product of soap industry used in cosmetics | (f) Ethanol |
Match the items of column I with items of column II.
| Column I | Column II | |
| (i) | Methanol | (a) Conversion of phenol to o-hydroxysalicylic acid |
| (ii) | Kolbe’s reaction | (b) Ethyl alcohol |
| (iii) | Williamson’s synthesis | (c) Conversion of phenol to salicylaldehyde |
| (iv) | Conversion of 2° alcohol to ketone | (d) Wood spirit |
| (v) | Reimer-Tiemann reaction | (e) Heated copper at 573 K |
| (vi) | Fermentation | (f) Reaction of alkyl halide with sodium alkoxide |
Assertion: Ethanol is a weaker acid than phenol.
Reason: Sodium ethoxide may be prepared by the reaction of ethanol with aqueous \[\ce{NaOH}\].
Convert the following:
Propanenitrile to ethanol.
If the starting material is 1-methyl-1,2-epoxy cyclopentane, of absolute configuration, decide which one compound correctly represents the product of its reaction with sodium methoxide in methanol.
Convert the following Ethanal to ethanol.
Give IUPAC names of the following compounds:
\[\begin{array}{cc}
\ce{CH3 - CH - CH - CH - CH2-OH }\\
|\phantom{......}|\phantom{......}|\phantom{.......}\\
\ce{Cl}\phantom{....}\ce{CH3}\phantom{...}\ce{CH3}\phantom{.....}
\end{array}\]
