Advertisements
Advertisements
प्रश्न
Arrange water, ethanol and phenol in increasing order of acidity and give reason for your answer.
Advertisements
उत्तर
The increasing order of acidity is ethanol < water < phenol. The phenoxide ion obtained after the removal of a proton is stabilised by resonance whereas the ethoxide ion obtained after the removal of a proton is destabilised by the ‘+I’ effect of the —C2H5 group. Therefore phenol is a stronger acid than ethanol. On the other hand, ethanol is a weaker acid than water because the electron-releasing —C2H5 group in ethanol increases the electron density on oxygen and hence the polarity of the O—H bond in ethanol decreases which results in the decreasing acidic strength. Hence acidic strength increases in the order given above.
APPEARS IN
संबंधित प्रश्न
Among the following the one which reacts most readily with ethanol is:
Methanol and ethanol are miscible in water due to ____________.
Which of the following is correct?
Phenol can be distinguished from ethanol by the reactions with:
(i) \[\ce{Br2/water}\]
(ii) \[\ce{Na}\]
(iii) Neutral \[\ce{FeCl3}\]
(iv) All the above
What is denatured alcohol?
Out of 2-chloroethanol and ethanol which is more acidic and why?
Suggest a reagent for conversion of ethanol to ethanal.
Suggest a reagent for conversion of ethanol to ethanoic acid.
Dipole moment of phenol is smaller than that of methanol. Why?
Match the items of column I with items of column II.
| Column I | Column II | |
| (i) | Antifreeze used in car engine | (a) Neutral ferric chloride |
| (ii) | Solvent used in perfumes | (b) Glycerol |
| (iii) | Starting material for picric acid | (c) Methanol |
| (iv) | Wood spirit | (d) Phenol |
| (v) | Reagent used for detection of phenolic group | (e) Ethleneglycol |
| (vi) | By product of soap industry used in cosmetics | (f) Ethanol |
Which reagent can convert acetic acid into ethanol?
Write chemical reactions of following reagents on methoxyethane:
dilute H2SO4
If the starting material is 1-methyl-1,2-epoxy cyclopentane, of absolute configuration, decide which one compound correctly represents the product of its reaction with sodium methoxide in methanol.
Convert the following Ethanal to ethanol.
Give IUPAC names of the following compounds:
\[\begin{array}{cc}
\ce{CH3 - CH - CH - CH - CH2-OH }\\
|\phantom{......}|\phantom{......}|\phantom{.......}\\
\ce{Cl}\phantom{....}\ce{CH3}\phantom{...}\ce{CH3}\phantom{.....}
\end{array}\]
3, 3-dimethyl-1-butene was subject to following reactions:
