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प्रश्न
Out of 2-chloroethanol and ethanol which is more acidic and why?
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उत्तर
The acidic character of alcohols is due to the polar nature of \[\ce{O - H}\] bond. 2-Chloroethanol, is more acidic due to \[\ce{-I}\] effect of chlorine atom. It increases the polarity of \[\ce{O - H}\] bond and increases the acidic strength.
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संबंधित प्रश्न
Give simple chemical test to distinguish between Ethanol and Phenol.
Among the following the one which reacts most readily with ethanol is:
Methanol and ethanol are miscible in water due to ____________.
Phenol can be distinguished from ethanol by the reactions with:
(i) \[\ce{Br2/water}\]
(ii) \[\ce{Na}\]
(iii) Neutral \[\ce{FeCl3}\]
(iv) All the above
What is denatured alcohol?
Suggest a reagent for conversion of ethanol to ethanal.
Arrange the following compounds in increasing order of acidity and give a suitable explanation.
Phenol, o-nitrophenol, o-cresol
The carbon-oxygen bond in phenol is slightly stronger than that in methanol. Why?
Match the items of column I with items of column II.
| Column I | Column II | |
| (i) | Antifreeze used in car engine | (a) Neutral ferric chloride |
| (ii) | Solvent used in perfumes | (b) Glycerol |
| (iii) | Starting material for picric acid | (c) Methanol |
| (iv) | Wood spirit | (d) Phenol |
| (v) | Reagent used for detection of phenolic group | (e) Ethleneglycol |
| (vi) | By product of soap industry used in cosmetics | (f) Ethanol |
Match the items of column I with items of column II.
| Column I | Column II | |
| (i) | Methanol | (a) Conversion of phenol to o-hydroxysalicylic acid |
| (ii) | Kolbe’s reaction | (b) Ethyl alcohol |
| (iii) | Williamson’s synthesis | (c) Conversion of phenol to salicylaldehyde |
| (iv) | Conversion of 2° alcohol to ketone | (d) Wood spirit |
| (v) | Reimer-Tiemann reaction | (e) Heated copper at 573 K |
| (vi) | Fermentation | (f) Reaction of alkyl halide with sodium alkoxide |
Assertion: Ethanol is a weaker acid than phenol.
Reason: Sodium ethoxide may be prepared by the reaction of ethanol with aqueous \[\ce{NaOH}\].
Convert the following:
Propanenitrile to ethanol.
Liquor poisoning is due to
Alcoholic fermentation is brought about by the action of
Write chemical reactions of following reagents on methoxyethane:
dilute H2SO4
If the starting material is 1-methyl-1,2-epoxy cyclopentane, of absolute configuration, decide which one compound correctly represents the product of its reaction with sodium methoxide in methanol.
How methanol is obtained from methanal.
