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Karnataka Board PUCPUC Science 2nd PUC Class 12

Write the mechanism of acid-catalysed dehydration of ethanol to yield ethene.

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Question

Write the mechanism of acid-catalysed dehydration of ethanol to yield ethene.

Chemical Equations/Structures
Short Answer
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Solution

In the presence of conc. acids such as H3PO4 and H2SO4 alcohols undergo dehydration to yield alkenes.

\[\ce{\underset{Ethanol}{H3C - CH2 - OH} ->[conc{.} H+/\Delta] \underset{Ethene}{CH2 = CH2} + H2O}\]

The mechanism for this reaction is:

Step 1: Protonation of ethanol:

Step 1: Formation of carbocation:

Step 3: Formation of ethene and regeneration of proton:

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Chapter 7: Alcohols, Phenols and Ethers - Exercises [Page 223]

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NCERT Chemistry Part 1 and 2 [English] Class 12
Chapter 7 Alcohols, Phenols and Ethers
Exercises | Q 7.19 | Page 223

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