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प्रश्न
Write a short note.
Homologous series
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उत्तर
- The series of carbon compounds formed by joining the same functional group in the place of a particular hydrogen atom on the carbon chains having sequentially increasing length is called homologous series.
- There are different homologous series in accordance with the functional group. For example, homologous series of alcohols, homologous series of carboxylic acids, homologous series of aldehydes, etc.
- All the members of the homologous series are homologues of each other and they can be represented by the same general molecular formula.
- Physical properties generally show a gradual change with the increase in molecular mass in the series whereas chemical properties of the members of the series show similarity because of the presence of the same functional group in them.
APPEARS IN
संबंधित प्रश्न
Write the next homologue of the following: C2H4
Write the next homologue of the following: C4H6
Write the name and formula of the 2nd member of homologous series having general formula CnH2n – 2.
Write the molecular formula of the 2nd and 3rd member of the homologous series where the first member is ethyne.
What is the difference between two consecutive homologues:
(i) in terms of molecular mass?
(ii) in terms of number and kind of atoms per molecule?
Give the name and structural formula of one homologue of the following:
CH3OH
The molecular formula of an organic compound is C18H36. Name its homologous series.
The molecular formula of a homologue of butane is ______.
A colourless organic liquid X of molecular formula C2H4O2 turns blue litmus to red. Another colourless organic liquid Y of molecular formula C3H6O has no action on any litmus but it is used as a nail polish remover. A yet another colourless organic liquid Z of molecular formula C2H6O has also no action on litmus but it is used in tincture of iodine.
(a) Name the liquid X. To which homologous series does it belong? Give the name of another member of this homologous series.
(b) Name the liquid Y. To which homologous series does it belong? Write the name of another member of this homologous series.
(c) Can you name an organic compound having the same molecular formula as liquid Y but which belongs to a different homologous series? What is this homologous series?
(d) Name the liquid Z. To which homologous series does it belong? Write the name of another member of this homologous series.
Give the names of the first four members of the homologous series of
alkynes.
Copy and complete the following table, which relates to the three homologous series of hydrocarbons:
| General formula | CnH2n | CnH2n-2 | CnH2n+2 |
| IUPAC name of the homologus series | |||
| Characteristic bond type | Single bonds | ||
| IUPAC name of the first member of the series | |||
| Type of reaction with chlorine | Addition |
Complete the following table for homologous series of alcohols.
| Name | Molecular formula | Condensed structural formula | Number of carbon atom | Number of -CH2- units | Boiling point °C |
| Methanol | CH4O | CH3-OH | 1 | 1 | 63 |
| Ethanol | C2H6O | CH3–CH2-OH | 2 | 2 | 78 |
| Propanol | C3H8O | CH3–CH2–CH2-OH | ______ | ______ | 97 |
| Butanol | C4H10O | CH3–CH2–CH2–CH2–OH | ______ | ______ | 118 |
Complete the following table for homologous series of Alkenes.
| Name | Molecular formula | Condensed structural formula | Number of carbon atom | Number of -CH2- units | Boiling point °C |
| Ethene | C2H4 | CH2 = CH2 | 2 | 0 | -102 |
| Propene | C3H6 | CH3–CH = CH2 | 3 | 1 | -48 |
| 1-Butene | C4H8 | CH3–CH2–CH = CH2 | ______ | ______ | -6.5 |
| 1-Pentene | C5H10 | CH3–CH2–CH2–CH = CH2 | ______ | ______ | 30 |
Complete the following chart by using examples given in brackets.
(isobutylene, cyclohexane, propane, cyclohexene, cyclopentane, benzene, propyne, isobutane, propene)
| Straight chain hydrocarbons | Branched chain hydrocarbons | Cyclic hydrocarbons |
What is called homologous series? Give any three of its characteristics?
Successive members of a homologous series vary by how many atomic mass unit?
C3H8 belongs to the homologous series of ______.
Define a homologous series.
Write the chemical formula of two consecutive homologous of organic compounds having functional group - OH.
What happens to the (i) boiling point and (ii) solubility of organic compounds of a homologous series as the molecular mass increases?
