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प्रश्न
Write a short note.
Homologous series
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उत्तर
- The series of carbon compounds formed by joining the same functional group in the place of a particular hydrogen atom on the carbon chains having sequentially increasing length is called homologous series.
- There are different homologous series in accordance with the functional group. For example, homologous series of alcohols, homologous series of carboxylic acids, homologous series of aldehydes, etc.
- All the members of the homologous series are homologues of each other and they can be represented by the same general molecular formula.
- Physical properties generally show a gradual change with the increase in molecular mass in the series whereas chemical properties of the members of the series show similarity because of the presence of the same functional group in them.
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संबंधित प्रश्न
What is meant by homologous series of carbon compounds?
Write the molecular formula of two consecutive members of homologous series of aldehydes. State which part of these compounds determines their
- physical and
- chemical properties
Write the molecular formula of the 2nd and 3rd member of the homologous series where the first member is ethyne.
Fill in the following blank with suitable word:
Ethene and ethyne are examples of ..... hydrocarbons.
Fill in the following blank with suitable word:
Carbon compounds have usually ... melting points and boiling points because they are ...... in nature.
Give the molecular formula of one homologue of each of the following:
C2H6
Write the names and formulae for the first three members of the homologous series for chloroalkanes.
Distinguish between homologous organs and analogous organs. In which category would you place wings of a bird and wings of a bat? Justify your answer giving a suitable reason.
Haloalkanes react with alkalies to produce alcohol. Give the equation for the preparation of the second member of the homologous series of alcohol. State under what condition the reaction occurs.
While going in an increasing order there is a rise in the molecular mass of the consecutive members of the homologous series by _______.
As one ascends in any homologous series, physical properties change gradually.
Complete the following table for the homologous series of alkanes.
| Name | Molecular formula | Condensed structural formula | Number of carbon atom | Number of -CH2- units | Boiling point °C |
| Methane | CH4 | CH4 | 1 | 1 | -162 |
| Ethane | C2H6 | CH3–CH3 | 2 | 2 | -88.5 |
| Propane | C3H8 | CH3–CH2–CH3 | 3 | 3 | -42 |
| Butane | C4H10 | CH3–CH2–CH2–CH3 | ______ | ______ | 0 |
| Pentane | C5H12 | CH3–CH2–CH2–CH2–CH3 | ______ | ______ | 36 |
| Hexane | C6H14 | CH3–CH2–CH2–CH2–CH2–CH3 | ______ | ______ | 69 |
Complete the following table for homologous series of Alkenes.
| Name | Molecular formula | Condensed structural formula | Number of carbon atom | Number of -CH2- units | Boiling point °C |
| Ethene | C2H4 | CH2 = CH2 | 2 | 0 | -102 |
| Propene | C3H6 | CH3–CH = CH2 | 3 | 1 | -48 |
| 1-Butene | C4H8 | CH3–CH2–CH = CH2 | ______ | ______ | -6.5 |
| 1-Pentene | C5H10 | CH3–CH2–CH2–CH = CH2 | ______ | ______ | 30 |
What is called homologous series? Give any three of its characteristics?
Successive members of a homologous series vary by how many atomic mass unit?
Which of the following does not belong to the same homologous series?
A carbon compound ‘A’ having melting point 156K and boiling point 351K, with molecular formula C2H6O is soluble in water in all proportions.
- Identify ‘A’ and draw its electron dot structure.
- Give the molecular formulae of any two homologues of ‘A’.
Write the chemical formula of two consecutive homologous of organic compounds having functional group - OH.
What happens to the (i) boiling point and (ii) solubility of organic compounds of a homologous series as the molecular mass increases?
Consider the following molecular formulae of carbon compounds:
(i) CH3COOH (ii) CH3OH (iii) C2H6 (iv) C3H4 (v) C4H8
- Which one of these compounds belongs to homologous series of alcohols?
- Identify the compound having triple bond between carbon-carbon atoms.
- Write the molecular formula of the first member of the homologous series to which CH3COOH belongs.
- Write the general formula of the series to which the compound C4H8 belongs.
