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प्रश्न
Write a short note.
Homologous series
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उत्तर
- The series of carbon compounds formed by joining the same functional group in the place of a particular hydrogen atom on the carbon chains having sequentially increasing length is called homologous series.
- There are different homologous series in accordance with the functional group. For example, homologous series of alcohols, homologous series of carboxylic acids, homologous series of aldehydes, etc.
- All the members of the homologous series are homologues of each other and they can be represented by the same general molecular formula.
- Physical properties generally show a gradual change with the increase in molecular mass in the series whereas chemical properties of the members of the series show similarity because of the presence of the same functional group in them.
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संबंधित प्रश्न
What is a homologous series?
What is meant by homologous series of carbon compounds?
Write the name and formula of the 2nd member of homologous series having general formula CnH2n.
Write the name and formula of the 2nd member of homologous series having general formula CnH2n – 2.
Write the molecular formula of two consecutive members of homologous series of aldehydes. State which part of these compounds determines their
- physical and
- chemical properties
Write the molecular formula of first two members of homologous series having functional group – OH
The following vegetables are kept in a basket :
Potato, Tomato, Radish, Brinjal, Carrot, Bottle-gourd
Which two of these vegetables correctly represent the homologous structures?
(A) Carrot and Tomato
(B) Potato and Brinjal
(C) Radish and Carrot
(D) Radish and Bottle-gourd
Complete the following table which relates to the homologous series of hydrocarbons.
|
General Formula |
IUPAC name of the homologous series | Characteristic bond type | IUPAC name of the first member of the series |
| `C_nH_(2n-2)` | (A)________ | (B)______ | (C)______ |
| C_nH_(2n+1) | (B)________ | (E)______ | (F)______ |
Define a homologous series. Give the name and structural formula of one homologue of the following:
CH3OH
The molecular formula of a homologue of butane is:
(a) C4H8
(b) C3H6
(c) C4H6
(d) C3H8
A colourless organic liquid X of molecular formula C2H4O2 turns blue litmus to red. Another colourless organic liquid Y of molecular formula C3H6O has no action on any litmus but it is used as a nail polish remover. A yet another colourless organic liquid Z of molecular formula C2H6O has also no action on litmus but it is used in tincture of iodine.
(a) Name the liquid X. To which homologous series does it belong? Give the name of another member of this homologous series.
(b) Name the liquid Y. To which homologous series does it belong? Write the name of another member of this homologous series.
(c) Can you name an organic compound having the same molecular formula as liquid Y but which belongs to a different homologous series? What is this homologous series?
(d) Name the liquid Z. To which homologous series does it belong? Write the name of another member of this homologous series.
Give the abbreviated formula of the third member of the alcohol.
.
What is the difference in the molecular formula of any two adjacent homologues:
(i) In terms of molecular mass
(ii) In terms of number and kind of atoms per molecule?
Complete the following table for the homologous series of alkanes.
| Name | Molecular formula | Condensed structural formula | Number of carbon atom | Number of -CH2- units | Boiling point °C |
| Methane | CH4 | CH4 | 1 | 1 | -162 |
| Ethane | C2H6 | CH3–CH3 | 2 | 2 | -88.5 |
| Propane | C3H8 | CH3–CH2–CH3 | 3 | 3 | -42 |
| Butane | C4H10 | CH3–CH2–CH2–CH3 | ______ | ______ | 0 |
| Pentane | C5H12 | CH3–CH2–CH2–CH2–CH3 | ______ | ______ | 36 |
| Hexane | C6H14 | CH3–CH2–CH2–CH2–CH2–CH3 | ______ | ______ | 69 |
What is called homologous series? Give any three of its characteristics?
Name the following organic compound:
The first homologue whose general formula is CnH2n.
Consider the carbon compounds having following molecular formula:
(i) C3H6 (ii) C3H8 (iii) C4H6 (iv) C6H6 (v) C6H12
- State the number of double covalent bonds present in C3H8.
- Write the formula of first member of the homologous series to which the carbon compound C4H6 belongs.
- Which one of the above compounds forms a ring structure of carbon atoms?
- Identify, which of the above compounds, is a member of alkane series.
Name and draw the electron dot structure of first homologue of alkynes series.
Name the third homologue of alcohols.
