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प्रश्न
What is a homologous series?
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उत्तर
A homologous series is a group of organic compounds having a similar structure and similar chemical properties in which the successive compounds differ by a CH2 group.
Example:
HCOOH - Methanoic acid
CH3COOH - Ethanoic acid
CH3CH2COOH - Propanoic acid
संबंधित प्रश्न
State any four characteristics of a homologous series
Write the name and formula of the 2nd member of homologous series having general formula CnH2n – 2.
Give the molecular formula of one homologue of the following:
C3H6
A colourless organic liquid X of molecular formula C2H4O2 turns blue litmus to red. Another colourless organic liquid Y of molecular formula C3H6O has no action on any litmus but it is used as a nail polish remover. A yet another colourless organic liquid Z of molecular formula C2H6O has also no action on litmus but it is used in tincture of iodine.
(a) Name the liquid X. To which homologous series does it belong? Give the name of another member of this homologous series.
(b) Name the liquid Y. To which homologous series does it belong? Write the name of another member of this homologous series.
(c) Can you name an organic compound having the same molecular formula as liquid Y but which belongs to a different homologous series? What is this homologous series?
(d) Name the liquid Z. To which homologous series does it belong? Write the name of another member of this homologous series.
Give the names and the structural formula of the first three members of the homologous series of alkanes.
What is homologous series ?
Complete the following table for the homologous series of alkanes.
| Name | Molecular formula | Condensed structural formula | Number of carbon atom | Number of -CH2- units | Boiling point °C |
| Methane | CH4 | CH4 | 1 | 1 | -162 |
| Ethane | C2H6 | CH3–CH3 | 2 | 2 | -88.5 |
| Propane | C3H8 | CH3–CH2–CH3 | 3 | 3 | -42 |
| Butane | C4H10 | CH3–CH2–CH2–CH3 | ______ | ______ | 0 |
| Pentane | C5H12 | CH3–CH2–CH2–CH2–CH3 | ______ | ______ | 36 |
| Hexane | C6H14 | CH3–CH2–CH2–CH2–CH2–CH3 | ______ | ______ | 69 |
Study and complete the following table:
| Homologous series | Alkane | Alkyne |
| General formula | CnH2n+2 | 1. ______ |
| IUPAC name | 2. ______ | Ethyne |
| Common name | Marsh gas | 3. ______ |
Define Homologous series.
Consider the carbon compounds having following molecular formula:
(i) C2H2 (ii) C2H5 (iii) C3H7OH (iv) C2H6COOH (v) CH3CHO
- Identify which one of the above compounds, is a member of aldehyde series.
- Write the general formula of the series to which compound C2H2 belongs.
- Which one of the above compounds has triple bonds between carbon-carbon atoms?
- Write the molecular formula of the first member of the homologous series to which the compound C3H7OH belongs.
