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प्रश्न
Explain the following:
PbX2 is more stable than PbX4.
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उत्तर
Due to inert pair effect, +2 oxidation state of Pb is more stable than its +4 oxidation state. Consequently, PbX2 in which the oxidation state of Pb is +2 is more stable than PbX4 in which the oxidation state of Pb is +4.
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संबंधित प्रश्न
How can you explain higher stability of BCl3 as compared to TlCl3?
Suggest reasons why the B–F bond lengths in BF3 (130 pm) and `"BF"_4^(-)` (143 pm) differ.
What happens when BF3 is reacted with ammonia?
The geometry of a complex species can be understood from the knowledge of type of hybridisation of orbitals of central atom. The hybridisation of orbitals of central atom in [Be(OH)4]– and the geometry of the complex are respectively.
Which of the following oxides is acidic in nature?
A compound X, of boron reacts with NH3 on heating to give another compound Y which is called inorganic benzene. The compound X can be prepared by treating BF3 with Lithium aluminium hydride. The compounds X and Y are represented by the formulas.
Cement, the important building material is a mixture of oxides of several elements. Besides calcium, iron and sulphur, oxides of elements of which of the group (s) are present in the mixture?
When BCl3 is treated with water, it hydrolyses and forms [B[OH]4]– only whereas AlCl3 in acidified aqueous solution forms [Al(H2O)6]3+ ion. Explain what is the hybridisation of boron and aluminium in these species?
Explain the following:
Boron does not exist as B3+ ion.
Identify the compounds A, X and Z in the following reactions:
\[\ce{A + 2HCl + 5H2O -> 2NaCl + X}\]
Match the species given in Column I with the hybridisation given in Column II.
| Column I | Column II |
| (i) Boron in [B(OH)4]– | (a) sp2 |
| (ii) Aluminium in [Al(H2O)6]3+ | (b) sp3 |
| (iii) Boron in B2H6 | (c) sp3d2 |
| (iv) Carbon in Buckminsterfullerene | |
| (v) Silicon in \[\ce{SiO^{4-}4}\] | |
| (vi) Germanium in [GeCl6]2– |
Describe the general trends in the following properties of the elements in Groups 13 and 14.
Atomic size
Describe the general trends in the following properties of the elements in Groups 13 and 14.
Nature of halides
Account for the following observations:
Though fluorine is more electronegative than chlorine yet BF3 is a weaker Lewis acid than BCl3
Account for the following observations:
PbO2 is a stronger oxidising agent than SnO2
BCl3 exists as monomer whereas AlCl3 is dimerised through halogen bridging. Give reason. Explain the structure of the dimer of AlCl3 also.
A nonmetallic element of group 13, used in making bullet proof vests is extremely hard solid of black colour. It can exist in many allotropic forms and has unusually high melting point. Its trifluoride acts as Lewis acid towards ammonia. The element exihibits maximum covalency of four. Identify the element and write the reaction of its trifluoride with ammonia. Explain why does the trifluoride act as a Lewis acid.
