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Equation of State of a Perfect Gas

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Topics

Estimated time: 4 minutes
  • Ideal gas equation (Equation of state)
  • Other forms of equation of state
  • Van der Waals' gas equation
  • Universal gas constant
  • Gas laws
  • Boyle's law
  • Charles' law
  • Gay Lussac's law
  • Avogadro's law and number
CBSE: Class 12

Law: Charles' Law

Statement: If pressure remains constant, the volume of a given mass of gas increases or decreases by 1/273.15 of its volume at 0°C for each 1°C rise or fall in temperature.

V ∝ T or \[\frac {V}{T}\] = constant or \[\frac {V_1}{T_1}\] = \[\frac {V_2}{T_2}\]
Vt = V0(1 + \[\frac {t}{273.15}\])
  • Also: \[\frac {V}{T}\] = \[\frac {m}{ρT}\] = constant and ρT = constant, ρ1T1 = ρ2T2​.
  • V-T graph: straight line; V vs 1/T: hyperbola.
CBSE: Class 12

Law: Dalton's Law of Partial Pressures

Statement: The pressure exerted by a mixture of non-reactive gases is equal to the sum of partial pressures of each component gas present in the mixture.

P = P1 + P2 + P3 + ... 
  • Each gas in a mixture exerts the same pressure as if it alone occupied the container.
  • Applies only to non-reactive gas mixtures.
CBSE: Class 12

Law: Graham's Law of Diffusion

Statement: At the same temperature and pressure, the rate of diffusion of gas is inversely proportional to the square root of the density of the gas.

rd ∝ \[\frac {1}{\sqrt ρ}\]or \[\frac {r_1}{r_2}\] = \[\sqrt{\frac {P_2}{P_1}}\]

Since vrms ∝ \[\frac {1}{\sqrt ρ}\]​, rate of diffusion ∝ vrms.

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