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Mean Free Path

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Estimated time: 4 minutes
  • Free path
  • Mean free path
Maharashtra State Board: Class 11

Definition: Free Path

The distance travelled by a gas molecule between two successive collisions, during which it moves in a straight line with constant velocity, is called free path.

Maharashtra State Board: Class 11

Definition: Mean Free Path

The average distance traversed by a molecule between two successive collisions, obtained by dividing the total distance travelled during nn collisions by the number of collisions nn, is called mean free path (λ).

Maharashtra State Board: Class 11

Formula: Mean Free Path

Let λ1, λ2, λ3,…λn​ be the distances travelled by a gas molecule during nn collisions respectively, then the mean free path is:

λ = \[\frac {λ_1+λ_2+λ_3+⋯+λ_n}{n}\]
 
Variation of Mean Free Path:
  • Inversely with the density (ρ) of the gas:
    λ ∝ \[\frac {1}{ρ}\]

  • Inversely with the square of the diameter (dd) of the molecule:
    λ ∝ \[\frac {1}{d^2}\]

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