English

Formal Charge

Advertisements

Topics

Estimated time: 6 minutes
CBSE: Class 12
Maharashtra State Board: Class 12

Key Points: Formal Charge

Formal charge is a bookkeeping tool — it is the hypothetical charge on an atom in a Lewis structure assuming electrons in bonds are equally shared. It helps identify the most stable (lowest energy) Lewis structure.

\[F.C.=V.E.-N.E.-\frac{B.E.}{2}\]

where:

  • V.E. = Total number of valence electrons of the atom in a free state
  • N.E. = Total number of non-bonding (lone pair) electrons on that atom
  • B.E. = Total number of bonding (shared) electrons around that atom

Key rules:

  • The sum of formal charges in a neutral molecule = 0
  • The sum of formal charges in an ion = charge of that ion
  • The most stable Lewis structure has formal charges as close to zero as possible
  • Negative formal charge should be on the more electronegative atom

Example — CO₃²⁻ and Ozone (O₃): Both have multiple valid Lewis structures (resonance), and formal charges help identify the preferred one.

Shaalaa.com | Formal charge on atom

Shaalaa.com


Next video


Shaalaa.com


Formal charge on atom [00:10:55]
S
Series: series 1
0%


Advertisements
Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×