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Karnataka Board PUCPUC Science 2nd PUC Class 12

PUC Science 2nd PUC Class 12 - Karnataka Board PUC Question Bank Solutions for Chemistry

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Chemistry
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Write a short note on the following:

Hoffmann’s bromamide reaction

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

Accomplish the following conversion:

Nitrobenzene to benzoic acid

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

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Accomplish the following conversion:

Benzyl chloride to 2-phenylethanamine

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

Accomplish the following conversion:

Benzamide to toluene

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

Give the structure of A, B and C in the following reaction:

\[\ce{CH3CH2I ->[NaCN] A ->[OH-][Partial hydrolysis] B ->[NaOH + Br2] C}\]

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

Give the structure of A, B and C in the following reaction:

\[\ce{C6H5N2Cl ->[CuCN] A ->[H2O/H+] B ->[NH3][\Delta] C}\]

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

Give the structure of A, B and C in the following reaction:

\[\ce{CH3CH2Br ->[KCN] A ->[LiAlH4] B ->[HNO2][0^\circ C] C}\]

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

Give the structure of A, B and C in the following reaction:

\[\ce{C6H5NO2 ->[Fe/HCl] A ->[NaNO2 + HCl][273 K] B ->[H2O/H+][\Delta] C}\]

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

Give the structures of A, B and C in the following reaction:

\[\ce{CH3COOH ->[NH3][\Delta] A ->[NaOBr] B ->[NaNO2/HCl] C}\]

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

Give the structures of A, B and C in the following reaction:

\[\ce{C6H5NO2 ->[Fe/HCl] A ->[HNO2][273 K] B ->[C6H5OH] C}\]

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

Why cannot aromatic primary amines be prepared by Gabriel phthalimide synthesis?

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

Write the reaction of aromatic primary amine with nitrous acid.

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

Write the reaction of aliphatic primary amine with nitrous acid.

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

Give a plausible explanation for the following:

Why are amines less acidic than alcohols of comparable molecular masses?

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

Write the structure of the product of the following reaction:

\[\ce{H3C - C ≡ C - H ->[Hg^{2+}, H2SO4]}\]

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Complete the synthesis by giving missing starting material, reagent or product.

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Complete the synthesis by giving missing starting material, reagent or product.

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Complete the synthesis by giving missing starting material, reagent or product.

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Show how is the following alcohol prepared by the reaction of a suitable Grignard reagent on methanal?

\[\begin{array}{cc}
\ce{CH3 - CH - CH2OH}\\
|\phantom{......}\\
\ce{CH3}\phantom{...}
\end{array}\]

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
Concept: undefined >> undefined

Show how is the following alcohol prepared by the reaction of a suitable Grignard reagent on methanal?

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
Concept: undefined >> undefined
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