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Karnataka Board PUCPUC Science 2nd PUC Class 12

PUC Science 2nd PUC Class 12 - Karnataka Board PUC Question Bank Solutions for Chemistry

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Chemistry
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What is meant by the term ‘coordination number’?

[1] Solid State
Chapter: [1] Solid State
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How would you determine the standard electrode potential of the system Mg2+ | Mg?

[2] Electrochemistry
Chapter: [2] Electrochemistry
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Consult the table of standard electrode potentials and suggest three substances that can oxidise ferrous ions under suitable conditions.

[2] Electrochemistry
Chapter: [2] Electrochemistry
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Calculate the standard cell potential of a galvanic cell in which the following reaction takes place:

\[\ce{2Cr_{(s)} + 3Cd{^{2+}_{(aq)}} -> 2Cr{^{3+}_{(aq)}} + 3Cd_{(s)}}\]

Calculate the ΔrG° and equilibrium constant of the reaction.

[2] Electrochemistry
Chapter: [2] Electrochemistry
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Write any two characteristics of chemisorption.

[5] Surface Chemistry
Chapter: [5] Surface Chemistry
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Why are powdered substances more effective adsorbents than their crystalline forms?

[5] Surface Chemistry
Chapter: [5] Surface Chemistry
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Distinguish between the meaning of the terms adsorption and absorption. Give one example of.

[5] Surface Chemistry
Chapter: [5] Surface Chemistry
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What is the difference between physisorption and chemisorption?

[5] Surface Chemistry
Chapter: [5] Surface Chemistry
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Give reason why a finely divided substance is more effective as an adsorbent.

[5] Surface Chemistry
Chapter: [5] Surface Chemistry
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What are the factors which influence the adsorption of a gas on a solid?

[5] Surface Chemistry
Chapter: [5] Surface Chemistry
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Discuss the effect of temperature on the adsorption of gases on solids.

[5] Surface Chemistry
Chapter: [5] Surface Chemistry
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In the series Sc (Z = 21) to Zn (Z = 30), the enthalpy of atomization of zinc is the lowest, i.e., 126 kJ mol−1. Why?

[4] d-block and f-block Elements
Chapter: [4] d-block and f-block Elements
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Which of the 3d series of the transition metals exhibits the largest number of oxidation states and why?

[4] d-block and f-block Elements
Chapter: [4] d-block and f-block Elements
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The \[\ce{E^{\circ}_{(M^{2+}/M)}}\] value for copper is positive (+0.34 V). What is possible reason for this? (Hint: consider its high ΔaH° and low ΔhydH°)

[4] d-block and f-block Elements
Chapter: [4] d-block and f-block Elements
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How would you account for the irregular variation of ionization enthalpies (first and second) in the first series of the transition elements?

[4] d-block and f-block Elements
Chapter: [4] d-block and f-block Elements
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Why is the highest oxidation state of a metal exhibited in its oxide or fluoride only?

[4] d-block and f-block Elements
Chapter: [4] d-block and f-block Elements
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Which is a stronger reducing agent, Cr2+ or Fe2+ and why?

[4] d-block and f-block Elements
Chapter: [4] d-block and f-block Elements
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Calculate the ‘spin only’ magnetic moment of \[\ce{M^{2+}_{( aq)}}\] ion (Z = 27).

[4] d-block and f-block Elements
Chapter: [4] d-block and f-block Elements
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Explain why Cu+ ion is not stable in aqueous solutions?

[4] d-block and f-block Elements
Chapter: [4] d-block and f-block Elements
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Why are Mn2+ compounds more stable than Fe2+ towards oxidation to their +3 state?

[4] d-block and f-block Elements
Chapter: [4] d-block and f-block Elements
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