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Science (English Medium) Class 12 - CBSE Question Bank Solutions for Chemistry

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Chemistry
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What happens when reaction:

Aniline reacts with chloroform in the presence of alcoholic potassium hydroxide

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

Cross aldol condensation occurs between

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

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What is the no. of possible isomers for the octahedral complex [Co(NH3)2(C2O4)2]?

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
Concept: undefined >> undefined

Explain how and why will the rate of reaction for a given reaction be affected when a catalyst is added.

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
Concept: undefined >> undefined

Using Valence bond theory, explain the following in relation to the paramagnetic complex [Mn(CN)6]3− 

  1. type of hybridization
  2. magnetic moment value
  3. type of complex – inner, outer orbital complex
[5] Coordination Compounds
Chapter: [5] Coordination Compounds
Concept: undefined >> undefined

Identify the major product formed when 2-cyclohexylchloroethane undergoes a dehydrohalogenation reaction. Name the reagent which is used to carry out the reaction.

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

Arrange the following in the increasing order of their property indicated:

4-Nitrobenzoic acid, benzoic acid, 3,4-Dinitrobenzoic acid, 4-Methoxy benzoic acid (Acid strength)

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
Concept: undefined >> undefined

Convert the following:

Acetaldehyde to But-2-enal

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Predict the reagent for carrying out the following transformations:

Ethanal to 3-hydroxy butanal

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Using valence bond theory, predict the hybridization and magnetic character of the following:

[CoF6]3– [Atomic number of Co = 27]

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
Concept: undefined >> undefined

The conversion of an alkyl halide into an alkene by alcoholic KOH is classified as ______.

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

Which of the following does not give aldol condensation reaction?

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

For the reaction 3A `rightarrow` 2B, rate of reaction `+ (d[B])/(dt)` is equal to ______.

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
Concept: undefined >> undefined

Write the hybridisation and magnetic behaviour of [CoF6]3−.

[Given: Atomic number of Co = 27]

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
Concept: undefined >> undefined

Which of the following compounds will undergo self-condensation in the presence of dilute NaOH solution?

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

For the reaction \[\ce{3A -> 2B}\], rate of reaction `-("d"["A"])/"dt"` is equal to ______.

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
Concept: undefined >> undefined

Which one of the following has the lowest pKa value?

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
Concept: undefined >> undefined

The magnetic moment of [NiCl4]2− is ______.

[Atomic number: Ni = 28]

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
Concept: undefined >> undefined

For the pair phenol and cyclohexanol, answer the following:

Why is phenol more acidic than cyclohexanol?

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
Concept: undefined >> undefined

[Ni(CO)4] has tetrahedral geometry while [Ni(CN)4]2− has square planar, yet both exhibit diamagnetism. Explain.
[Atomic number: Ni = 28]

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
Concept: undefined >> undefined
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