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Question
Write a chemical reaction for the following conversion:
Acetic acid into ethyl alcohol.
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Solution
\[\ce{\underset{Acetic acid}{CH3COOH} ->[(i) LiAlH4][(ii) H3O^⊕] \underset{Ethyl alcohol}{CH3CH2 - OH}}\]
RELATED QUESTIONS
What is metamerism?
Explain metamerism with suitable examples of ethers
Name the following compound according to IUPAC system.
\[\begin{array}{cc}
\phantom{............}\ce{CH2OH}\\
\phantom{......}|\\
\ce{CH3 - CH2 - CH - CH - CH - CH3}\\
\phantom{......}|\phantom{............}|\phantom{.}\\
\phantom{........}\ce{CH2Cl}\phantom{......}\ce{CH3}\phantom{}
\end{array}\]
Name the following compound according to IUPAC system.
\[\begin{array}{cc}
\ce{CH3 - C = C - CH2OH}\\
\phantom{}|\phantom{....}|\phantom{....}\\
\phantom{}\ce{CH3}\phantom{.}\ce{Br}\phantom{...}
\end{array}\]
Write IUPAC name of the following compound:
\[\begin{array}{cc}
\phantom{................}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3\phantom{.}}\phantom{..}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]
Write IUPAC name of the following compound:
\[\begin{array}{cc}
\ce{CH3 - CH - CH - CH3}\\
|\phantom{......}|\phantom{..}\\
\ce{OH}\phantom{...}\ce{OH}\phantom{}
\end{array}\]
Write IUPAC name of the following compound:
\[\begin{array}{cc}
\ce{HO - CH2 - CH - CH2 - OH}\\
|\phantom{..}\\
\ce{OH}
\end{array}\]
Write IUPAC name of the following compound:
Write IUPAC name of the following compound:
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- Draw the structures of all isomeric alcohols of molecular formula C5H12O and give their IUPAC names.
- Classify the isomers of alcohols in the above question as primary, secondary and tertiary alcohols.
Give IUPAC name of the following ether:
CH3OCH2CH2Cl
Give IUPAC name of the following ether:
CH3CH2CH2OCH3
Natalite is a mixture of
(a) diethyl ether and methanol
(b) diethyl ether and ethanol
(c) dimethyl ether and methanol
(d) dimethyl ether and ethanol
Which of the following compounds is NOT prepared by the action of alcoholic NI3 on alkyl halide?
(a) CH3NH2
(b) CH3- CH2- NH2
(c) CH3 - CH2 - CH2 - NH2
(d) (CH3)3 C- NH2
What is the action of hot HI on it?
3-Methylbutane-2-ol on heating with HI gives ______
How is phenol converted into the following?
Benzene
How is phenol converted into the following?
benzoquinone
How is phenol converted into the following?
picric acid
Write IUPAC name of the following compound (CH3)2 N − CH2CH3
Give reasons Fluoride ion has higher hydration enthalpy than chloride ion.
Write the IUPAC name of the following compound:
In the dehydration of alcohols to alkenes by heating with concentrated sulphuric acid, the initiation step is:
(1) formation of carbonation
(2) formation of an ester
(3) protonation of the alcohol molecule
(4) elimination of water
What.will be the product fonned when chlorobenzene is heated with sodium metal in the presence of dry ether?
Resorcinol on distillation with zinc dust gives _________.
Write structural formulae for Methyl vinyl ether.
Write structural formulae for 1-Ethylcyclohexanol.
Write structural formula for pentane-1,4-diol.
Write IUPAC name of the following
Write IUPAC names of the following
Write IUPAC names of the following
In a carbinol system of nomenclature tert.butyl alcohol is named as _______________
Isopropyl alcohol on oxidation forms:
Give IUPAC names of the following compound:
3-methylphenol is called ____________.
One of the following is not a dihydroxy derivative of benzene.
The compound HOCH2 – CH2OH is __________.
Butane-2-ol is ____________.
Which of the following compounds is oxidised to prepare methyl ethyl ketone?
n-Propyl alcohol and isopropyl alcohol can be chemically distinguished by which reagent?
Ethylene reacts with Baeyer’s reagent to give ______.
1-Propanol and 2-propanol can be best distinguished by:
The major product formed by the reaction:
\[\begin{array}{cc}
\ce{CH3CH-CH2Br ->[CH3O^-][CH3OH] is}\\
|\phantom{................}\\
\ce{CH3}\phantom{.............}
\end{array}\]
Which of the following gives a positive iodoform test?
\[\ce{Phenol ->[Zn, dust] 'X' ->[CH3Cl][Anhy. AlCl3] 'Y' ->[Alkaline][KMnO4] 'Z'}\]
The product ‘Z’ is:
IUPAC name of the compound is:
\[\begin{array}{cc}
\ce{CH3-CH-OCH3}\\
|\phantom{....}\\
\ce{CH3}\phantom{..}
\end{array}\]
The correct acidic strength order of the following is:
(I)
(II)
(III)
IUPAC name of m-cresol is ______.
IUPAC name of the compound \[\begin{array}{cc}
\ce{CH3 - CH - OCH3}\\
\phantom{}|\phantom{....}\\
\phantom{}\ce{CH3}\phantom{..}
\end{array}\] is ______.
Give IUPAC name of the compound given below.
\[\begin{array}{cc}
\phantom{}\ce{CH3 - CH - CH2 - CH2 - CH - CH3}\phantom{.}\\
\phantom{.........}|\phantom{...................}|\phantom{...........}\\
\phantom{..}\ce{Cl}\phantom{.................}\ce{OH}\phantom{..}
\end{array}\]
Which of the following compounds will react with sodium hydroxide solution in water?
Write the IUPAC name of the compound given below.
\[\begin{array}{cc}
\phantom{}\ce{CH3 - CH2 - C = C - OH}\\
\phantom{........}|\phantom{....}|\phantom{}\\
\phantom{..............}\ce{CH3 CH2OH}
\end{array}\]
Arrange the following compounds in decreasing order of acidity.
\[\ce{H2O, ROH, HC ≡ CH}\]
Write steps to carry out the conversion of phenol to aspirin.
Explain why p-nitrophenol is more acidic than phenol.
Match the structures of the compounds given in Column I with the name of the compounds given in Column II.
| Column I | Column II | |
| (i) |  |
(a) Hydroquinone |
| (ii) |  |
(b) Phenetole |
| (iii) |  |
(c) Catechol |
| (iv) |  |
(d) o-Cresol |
| (v) |  |
(e) guinone |
| (vi) |  |
(f) Resorcinol |
| (g) Anisole |
Match the starting materials given in Column I with the products formed by these (Column II) in the reaction with HI.
| Column I | Column II | ||
| (i) | CH3—O—CH3 | (a) |  |
| (ii) | \[\begin{array}{cc} \ce{CH3}\phantom{..................}\\ \backslash\phantom{.............}\\ \ce{CH-O-CH3}\\ /\phantom{..............}\\ \ce{CH3}\phantom{..................} \end{array}\] |
(b) | \[\begin{array}{cc} \ce{CH3}\phantom{....}\\ |\phantom{.......}\\ \ce{CH3-C-I + CH3OH}\\ |\phantom{.......}\\ \ce{CH3}\phantom{....} \end{array}\] |
| (iii) | \[\begin{array}{cc} \ce{CH3}\phantom{.}\\ |\phantom{....}\\ \ce{H3C-C-O-CH3}\\ |\phantom{....}\\ \ce{CH3}\phantom{..} \end{array}\] |
(c) |  |
| (iv) |  |
(d) | CH3—OH + CH3—I |
| (e) | \[\begin{array}{cc} \ce{CH3}\phantom{.....................}\\ \backslash\phantom{.................}\\ \ce{CH-OH + CH3I}\\ /\phantom{.................}\\ \ce{CH3}\phantom{.....................} \end{array}\] |
||
| (f) | \[\begin{array}{cc} \ce{CH3}\phantom{.....................}\\ \backslash\phantom{.................}\\ \ce{CH-I + CH3OH}\\ /\phantom{.................}\\ \ce{CH3}\phantom{.....................} \end{array}\] |
||
| (g) | \[\begin{array}{cc} \ce{CH3}\phantom{....}\\ |\phantom{.......}\\ \ce{CH3-C-OH + CH3I}\\ |\phantom{.......}\\ \ce{CH3}\phantom{....} \end{array}\] |
Assertion: Addition reaction of water to but-1-ene in acidic medium yields butan-1-ol.
Reason: Addition of water in acidic medium proceeds through the formation of primary carbocation.
Assertion: p-nitrophenol is more acidic than phenol.
Reason: Nitro group helps in the stabilisation of the phenoxide ion by dispersal of negative charge due to resonance.
Assertion: IUPAC name of the compound
\[\begin{array}{cc}
\ce{CH3 - CH - O - CH2 - CH2 - CH3}\\
|\phantom{....................}\\
\ce{CH3}\phantom{.................}
\end{array}\] is 2-Ethoxy-2-methylethane.
Reason: In IUPAC nomenclature, ether is regarded as hydrocarbon derivative in which a hydrogen atom is replaced by —OR or —OAr group [where R = alkyl group and Ar = aryl group]
Assertion: Phenol forms 2, 4, 6 – tribromophenol on treatment with \[\ce{Br2}\] in carbon disulphide at 273 K.
Reason: Bromine polarises in carbon disulphide.
Assertion: Phenols give o- and p-nitrophenol on nitration with conc. \[\ce{HNO3}\] and \[\ce{H2SO4}\] mixture.
Reason: –OH group in phenol is o–, p– directing.
Write complete reaction for the bromination of phenol in aqueous and non-aqueous medium.
How can phenol be converted to aspirin?
Write the IUPAC name of the following compound.
Convert the following:
Ethyl alcohol into ethyl acetate.
How are the following conversions carried out?
Methyl magnesium bromide→2-Methylpropan-2-ol.
Draw structure of the following compound.
2-Methoxypropane
Draw structure of the following compound.
Prop-2-en-1-ol
Write structural formulae for:
p-Nitrophenol
Write structural formulae for:
Salicylic acid
Write the IUPAC name of the following compound:
\[\begin{array}{cc}
\phantom{..............}\ce{CH3}\\
\phantom{............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{.....}|\phantom{......}|\\
\phantom{...}\ce{CH3}\phantom{.}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]
Write the IUPAC name of the following compound:
\[\begin{array}{cc}
\phantom{...............}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3}\phantom{..}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]
