Advertisements
Advertisements
प्रश्न

Which of the statements are correct about above reaction?
(i) (a) and (e) both are nucleophiles.
(ii) In (c) carbon atom is sp3 hybridised.
(iii) In (c) carbon atom is sp2 hybridised.
(iv) (a) and (e) both are electrophiles.
Advertisements
उत्तर
(i) (a) and (e) both are nucleophiles.
(iii) In (c) carbon atom is sp2 hybridised.
Explanation:
HO− and Cl− are nucleophiles.
In (iii), C atom is sp2 hybridised due to formation of \[\ce{C - OH}\] bond and breaking of \[\ce{C - Cl}\] bond simultaneously. So, in the transition state, the C atom is bonded to only 3 H atoms completely.
APPEARS IN
संबंधित प्रश्न
Discuss the mechanism of alkaline hydrolysis of bromomethane.
Write the structure of the major organic product in the following reaction:
\[\ce{CH3CH(Br)CH2CH3 + NaOH ->[water]}\]
Arrange the compounds of the following set in order of reactivity towards SN2 displacement:
2-Bromo-2-methylbutane, 1-Bromopentane, 2-Bromopentane
SN1 reactions are accompanied by racemization in optically active alkyl halides.
Which one of the following halogen compounds is difficult to be hydrolysed by SN1 mechanism?
Which of the following is an optically active compound?
2-Bromopentane is heated with potassium ethoxide in ethanol. The major product obtained is ____________.
SN1 reaction of alkyl halides lead to ___________.
The correct order of increasing the reactivity of C–X bond towards nucleophile in following compounds.

(I)

(II)
(CH3)3CCl
(III)
(CH3)2CHCl
(IV)
Ethylene chloride and ethylidene chloride are isomers. Identify the correct statements.
(i) Both the compounds form same product on treatment with alcoholic KOH.
(ii) Both the compounds form same product on treatment with aq.NaOH.
(iii) Both the compounds form same product on reduction.
(iv) Both the compounds are optically active.
Which of the compounds will react faster in SN1 reaction with the –OH ion?
\[\ce{CH3-CH2-Cl}\] or \[\ce{C6H5-CH2-Cl}\]
Write the structures and names of the compounds formed when compound ‘A’ with molecular formula, \[\ce{C7H8}\] is treated with \[\ce{Cl2}\] in the presence of \[\ce{FeCl3}\].
Aryl halides are extremely less reactive towards nucleophilic substitution. Predict and explain the order of reactivity of the following compounds towards nucleophilic substitution:
| (I) | ![]() |
| (II) | ![]() |
| (III) | ![]() |
Cyanide ion acts as an ambident nucleophile. From which end it acts as a stronger nucleophile in aqueous medium? Give reason for your answer.
Which one of the following compounds is more reactive towards SN1 reaction?
Inversion of configuration occurs in ______.
Which alkyl halide from the following pair would you expect to react more rapidly by an SN2 mechanism? Explain your answer.
\[\begin{array}{cc}
\ce{CH3CHCH2CH2Br}\\
|\phantom{.............}\\
\ce{CH3}\phantom{..........}\\
\end{array}\] or \[\begin{array}{cc}
\ce{CH3CH2CHCH2Br}\\
|\\
\phantom{...}\ce{CH3}\\
\end{array}\]
Assertion (A):
undergoes SN2 reactions faster than
.
Reason (R): Iodine is a better leaving group because of its large size.
In the light of the above statements, choose the correct answer from the options given below:



