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प्रश्न
How is phenol converted into the following?
picric acid
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उत्तर
Conversion of phenol into picric acid:
When phenol is treated with hot and conc. HNO3 in the presence of conc. H2SO4 (nitrating mixture), yellow coloured picric acid, i.e. 2,4,6-Trinitrophenol is obtained
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संबंधित प्रश्न
What is metamerism?
Write the IUPAC name of the given compound:
Name the following compound according to IUPAC system.
\[\begin{array}{cc}
\phantom{........................}\ce{CH2OH}\\
\phantom{..................}|\\
\ce{CH3 - CH - CH2 - CH - CH - CH3}\\
\phantom{}|\phantom{.............}|\phantom{........}\\
\phantom{..}\ce{CH3}\phantom{..........}\ce{OH}\phantom{........}
\end{array}\]
Name the following compound according to IUPAC system.
\[\begin{array}{cc}
\ce{CH3 - C = C - CH2OH}\\
\phantom{}|\phantom{....}|\phantom{....}\\
\phantom{}\ce{CH3}\phantom{.}\ce{Br}\phantom{...}
\end{array}\]
Write IUPAC name of the following compound:
\[\begin{array}{cc}
\phantom{................}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3\phantom{.}}\phantom{..}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]
Write IUPAC name of the following compound:
\[\begin{array}{cc}
\ce{H3C - CH - CH2 - CH - CH - CH2 - CH3}\\
\phantom{}|\phantom{.............}|\phantom{......}|\phantom{.........}\\
\phantom{}\ce{OH}\phantom{..........}\ce{OH}\phantom{...}\ce{C2H5}\phantom{......}
\end{array}\]
Write IUPAC name of the following compound:
\[\begin{array}{cc}
\ce{HO - CH2 - CH - CH2 - OH}\\
|\phantom{..}\\
\ce{OH}
\end{array}\]
Write IUPAC name of the following compound:
Write IUPAC name of the following compound:
Write IUPAC name of the following compound:
Write IUPAC name of the following compound:
C6H5 – O – C2H5
Write IUPAC name of the following compound:
\[\begin{array}{cc}
\ce{CH3 - CH2 - O - CH - CH2 - CH3}\\
\phantom{...}|\\
\phantom{.....}\ce{CH3}
\end{array}\]
Give IUPAC name of the following ether:
\[\begin{array}{cc}
\ce{C2H5OCH2 - CH - CH3}\\
\phantom{.....}|\\
\phantom{.......}\ce{CH3}
\end{array}\]
Give IUPAC name of the following ether:
CH3OCH2CH2Cl
Give IUPAC name of the following ether:
O2N – C6H4 – OCH3(p)
Give IUPAC name of the following ether:
CH3CH2CH2OCH3
Write the structure and IUPAC name of 'methyl-n-propyl ether'.
What is the action of hot HI on it?
3-Methylbutane-2-ol on heating with HI gives ______
How is phenol converted into the following?
Benzene
Write IUPAC name of the following compound (CH3)2 N − CH2CH3
Write the structures of the products when Butan-2-ol reacts with SOCl2
In the dehydration of alcohols to alkenes by heating with concentrated sulphuric acid, the initiation step is:
(1) formation of carbonation
(2) formation of an ester
(3) protonation of the alcohol molecule
(4) elimination of water
What.will be the product fonned when chlorobenzene is heated with sodium metal in the presence of dry ether?
Propanoic acid to ethylamine.
Resorcinol on distillation with zinc dust gives _________.
Write structural formulae for 1-Ethylcyclohexanol.
Write structural formula for pentane-1,4-diol.
Write IUPAC name of the following
Write IUPAC name of the following
\[\begin{array}{cc}\ce{CH3-CH-CH-CH2-OH}\\|\phantom{.....}|\phantom{.......}\\\ce{OH}\phantom{..}\ce{CH3}\phantom{.....}\end{array}\]
Write IUPAC names of the following
Write IUPAC names of the following
Glycerol is ____________.
Isopropyl alcohol on oxidation forms:
Give IUPAC names of the following compound:
Give IUPAC names of the following compound:
\[\begin{array}{cc}
\phantom{..}\ce{H}\phantom{...}\ce{CH3}\phantom{.}\ce{H}\phantom{..}\\
\phantom{}|\phantom{....}|\phantom{....}|\phantom{}\\
\ce{H - C - C - C - H}\\
\phantom{}|\phantom{....}|\phantom{....}|\phantom{}\\
\phantom{.}\ce{H}\phantom{...}\ce{OH}\phantom{.}\ce{H}\phantom{.}\\
\end{array}\]
3-methylphenol is called ____________.
One of the following is not a dihydroxy derivative of benzene.
An example of a compound with functional group – O – is ____________.
Butane-2-ol is ____________.
Cresol has ____________.
Ethyl alcohol is industrially prepared from ethylene by:
Which of the following compounds is oxidised to prepare methyl ethyl ketone?
HBr reacts fastest with ____________.
n-Propyl alcohol and isopropyl alcohol can be chemically distinguished by which reagent?
Ethylene reacts with Baeyer’s reagent to give ______.
When ethyl alcohol reacts with acetic acid, the products formed are:
1-Propanol and 2-propanol can be best distinguished by:
Which of the following is most acidic?
The IUPAC name of the ether CH2 = CH–CH2OCH3 is:
The major product formed by the reaction:
\[\begin{array}{cc}
\ce{CH3CH-CH2Br ->[CH3O^-][CH3OH] is}\\
|\phantom{................}\\
\ce{CH3}\phantom{.............}
\end{array}\]
\[\ce{HC ≡ CH ->[HgSO4][H2SO4] ->[CH3MgBr][H2O] ->[PBr3]}\]
The heating of phenyl methyl ether with HI produces:
Which of the following gives a positive iodoform test?
\[\ce{Phenol ->[Zn, dust] 'X' ->[CH3Cl][Anhy. AlCl3] 'Y' ->[Alkaline][KMnO4] 'Z'}\]
The product ‘Z’ is:
Among the following sets of reactants which one produces anisole?
IUPAC name of the compound \[\begin{array}{cc}
\ce{CH3 - CH - OCH3}\\
\phantom{}|\phantom{....}\\
\phantom{}\ce{CH3}\phantom{..}
\end{array}\] is ______.
Write the IUPAC name of the compound given below.
\[\begin{array}{cc}
\phantom{}\ce{CH3 - CH2 - C = C - OH}\\
\phantom{........}|\phantom{....}|\phantom{}\\
\phantom{..............}\ce{CH3 CH2OH}
\end{array}\]
Write steps to carry out the conversion of phenol to aspirin.
Explain why p-nitrophenol is more acidic than phenol.
Match the structures of the compounds given in Column I with the name of the compounds given in Column II.
| Column I | Column II | |
| (i) |  |
(a) Hydroquinone |
| (ii) |  |
(b) Phenetole |
| (iii) |  |
(c) Catechol |
| (iv) |  |
(d) o-Cresol |
| (v) |  |
(e) guinone |
| (vi) |  |
(f) Resorcinol |
| (g) Anisole |
Assertion: Addition reaction of water to but-1-ene in acidic medium yields butan-1-ol.
Reason: Addition of water in acidic medium proceeds through the formation of primary carbocation.
Assertion: Phenol forms 2, 4, 6 – tribromophenol on treatment with \[\ce{Br2}\] in carbon disulphide at 273 K.
Reason: Bromine polarises in carbon disulphide.
Assertion: Phenols give o- and p-nitrophenol on nitration with conc. \[\ce{HNO3}\] and \[\ce{H2SO4}\] mixture.
Reason: –OH group in phenol is o–, p– directing.
Write complete reaction for the bromination of phenol in aqueous and non-aqueous medium.
Explain why Lewis acid is not required in bromination of phenol?
Convert the following:
Ethyl alcohol into ethyl acetate.
Identify A and B in the following:
Draw structure of the following compound.
Prop-2-en-1-ol
Give the structures of Thiosulphuric acid and Peroxy monosulphuric acid.
Write structural formulae for:
p-Nitrophenol
Write structural formulae for:
Salicylic acid
The IUPAC name of 
is ______.
Write IUPAC name of the following compound:
\[\begin{array}{cc}
\phantom{...............}\ce{CH3}\\
\phantom{............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3}\phantom{...}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]
Write IUPAC names of the following compounds:
\[\begin{array}{cc}
\phantom{...............}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3\phantom{...}OH\phantom{...}CH3}\\
\end{array}\]
Write IUPAC name of the following compound:
\[\begin{array}{cc}
\phantom{................}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3}\phantom{...}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]
Write the IUPAC name of the following compound:
\[\begin{array}{cc}
\phantom{...............}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3}\phantom{..}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]
