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Which of the Following Compounds is Not Prepared by the Action of Alcoholic Ni3 on Alkyl Halide - Chemistry

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प्रश्न

Which of the following compounds is NOT prepared by the action of alcoholic NI3 on alkyl halide?

(a) CH3NH2

(b) CH3- CH2- NH2

(c) CH3 - CH2 - CH2 - NH2

(d) (CH3)C- NH2

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उत्तर

(CH3)3C – NH2

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2015-2016 (July)

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व्हिडिओ ट्यूटोरियलVIEW ALL [3]

संबंधित प्रश्‍न

What is metamerism? 


Write the IUPAC name of the given compound:


Name the following compound according to IUPAC system.

\[\begin{array}{cc}
\phantom{............}\ce{CH2OH}\\
\phantom{......}|\\
\ce{CH3 - CH2 - CH - CH - CH - CH3}\\
\phantom{......}|\phantom{............}|\phantom{.}\\
\phantom{........}\ce{CH2Cl}\phantom{......}\ce{CH3}\phantom{}
\end{array}\]


Name the following compound according to IUPAC system.


Name the following compound according to IUPAC system.

\[\begin{array}{cc}
\ce{CH3 - C = C - CH2OH}\\
\phantom{}|\phantom{....}|\phantom{....}\\
\phantom{}\ce{CH3}\phantom{.}\ce{Br}\phantom{...}
\end{array}\]


Write IUPAC name of the following compound:

\[\begin{array}{cc}
\phantom{................}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3\phantom{.}}\phantom{..}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]


Write IUPAC name of the following compound:


Write IUPAC name of the following compound:

\[\begin{array}{cc}
\ce{CH3 - O - CH2 - CH - CH3}\\
\phantom{..........}|\\
\phantom{............}\ce{CH3}
\end{array}\]


Write IUPAC name of the following compound:

C6H5 – O – C2H5


Write structures of the compounds whose IUPAC names are as follows:

3-Chloromethylpentan-1-ol.


  1. Draw the structures of all isomeric alcohols of molecular formula C5H12O and give their IUPAC names.
  2. Classify the isomers of alcohols in the above question as primary, secondary and tertiary alcohols.

Give IUPAC name of the following ether:

\[\begin{array}{cc}
\ce{C2H5OCH2 - CH - CH3}\\
\phantom{.....}|\\
\phantom{.......}\ce{CH3}
\end{array}\]


Give IUPAC name of the following ether:

CH3OCH2CH2Cl


Give IUPAC name of the following ether:

CH3CH2CH2OCH3


Give IUPAC name of the following ether:


Ethylidene dichloride when boiled with aqueous solution of NaOH yields _______.

(A) formaldehyde

(B) acetaldehyde

(C) acetone

(D) ethyl methyl ketone


Natalite is a mixture of

(a) diethyl ether and methanol

(b) diethyl ether and ethanol

(c) dimethyl ether and methanol

(d) dimethyl ether and ethanol


Write the structure and IUPAC name of 'methyl-n-propyl ether'.


How is phenol converted into the following?

Benzene


How is phenol converted into the following?

benzoquinone


How is phenol converted into the following?

picric acid


Write the structures of the products when Butan-2-ol reacts with CrO3


Write the structures of the products when Butan-2-ol reacts with SOCl2


What.will be the product fonned when chlorobenzene is heated with sodium metal in the presence of dry ether?


Propanoic acid to ethylamine.


Write structural formulae for 3-Methoxyhexane


Write structural formulae for Methyl vinyl ether.


Write structural formulae for 1-Ethylcyclohexanol.


Write structural formulae for Cyclohex-2-en-1-ol.


Write IUPAC name of the following


Write IUPAC name of the following

\[\begin{array}{cc}\ce{CH3-CH-CH-CH2-OH}\\|\phantom{.....}|\phantom{.......}\\\ce{OH}\phantom{..}\ce{CH3}\phantom{.....}\end{array}\]


Write IUPAC names of the following


In a carbinol system of nomenclature tert.butyl alcohol is named as _______________


Glycerol is ____________.


Isopropyl alcohol on oxidation forms:


Give IUPAC names of the following compound:

\[\begin{array}{cc}
\phantom{..}\ce{H}\phantom{...}\ce{CH3}\phantom{.}\ce{H}\phantom{..}\\
\phantom{}|\phantom{....}|\phantom{....}|\phantom{}\\
\ce{H - C - C - C - H}\\
\phantom{}|\phantom{....}|\phantom{....}|\phantom{}\\
\phantom{.}\ce{H}\phantom{...}\ce{OH}\phantom{.}\ce{H}\phantom{.}\\
\end{array}\]


C6H5OCH2CH3 is called:


3-methylphenol is called ____________.


The compound HOCH2 – CH2OH is __________.


Butane-2-ol is ____________.


Cresol has ____________.


Which of the following compounds is oxidised to prepare methyl ethyl ketone?


HBr reacts fastest with ____________.


Ethylene reacts with Baeyer’s reagent to give ______.


When ethyl alcohol reacts with acetic acid, the products formed are:


1-Propanol and 2-propanol can be best distinguished by:


Which of the following is most acidic?


The IUPAC name of the ether CH2 = CH–CH2OCH3 is:


\[\ce{HC ≡ CH ->[HgSO4][H2SO4] ->[CH3MgBr][H2O] ->[PBr3]}\]


The product of acid catalysed hydration of 2-phenylpropene is:


The heating of phenyl methyl ether with HI produces:


Which of the following gives a positive iodoform test?


\[\ce{Phenol ->[Zn, dust] 'X' ->[CH3Cl][Anhy. AlCl3] 'Y' ->[Alkaline][KMnO4] 'Z'}\]

The product ‘Z’ is:


Among the following sets of reactants which one produces anisole?


IUPAC name of the compound is:

\[\begin{array}{cc}
\ce{CH3-CH-OCH3}\\
|\phantom{....}\\
\ce{CH3}\phantom{..}
\end{array}\]


Which of the following compounds will react with sodium hydroxide solution in water?


Which of the following reagents can be used to oxidise primary alcohols to aldehydes?

(i) \[\ce{CrO3}\] in anhydrous medium.

(ii) \[\ce{KMnO4}\] in acidic medium.

(iii) Pyridinium chlorochromate.

(iv) Heat in the presence of Cu at 573 K.


Write the IUPAC name of the compound given below.

\[\begin{array}{cc}
\phantom{}\ce{CH3 - CH2 - C = C - OH}\\
\phantom{........}|\phantom{....}|\phantom{}\\
\phantom{..............}\ce{CH3 CH2OH}
\end{array}\]


Arrange the following compounds in decreasing order of acidity.

\[\ce{H2O, ROH, HC ≡ CH}\]


Explain why p-nitrophenol is more acidic than phenol.


Match the structures of the compounds given in Column I with the name of the compounds given in Column II.

  Column I Column II
(i) (a) Hydroquinone
(ii) (b) Phenetole
(iii) (c) Catechol
(iv) (d) o-Cresol
(v) (e) guinone
(vi) (f) Resorcinol
    (g) Anisole

Match the starting materials given in Column I with the products formed by these (Column II) in the reaction with HI.

  Column I   Column II
(i) CH3—O—CH3 (a)
(ii) \[\begin{array}{cc}
\ce{CH3}\phantom{..................}\\
\backslash\phantom{.............}\\
\ce{CH-O-CH3}\\
/\phantom{..............}\\
\ce{CH3}\phantom{..................}
\end{array}\]
(b) \[\begin{array}{cc}
\ce{CH3}\phantom{....}\\
|\phantom{.......}\\
\ce{CH3-C-I + CH3OH}\\
|\phantom{.......}\\
\ce{CH3}\phantom{....}
\end{array}\]
(iii) \[\begin{array}{cc}
\ce{CH3}\phantom{.}\\
|\phantom{....}\\
\ce{H3C-C-O-CH3}\\
|\phantom{....}\\
\ce{CH3}\phantom{..}
\end{array}\]
(c)
(iv) (d) CH3—OH + CH3—I
    (e) \[\begin{array}{cc}
\ce{CH3}\phantom{.....................}\\
\backslash\phantom{.................}\\
\ce{CH-OH + CH3I}\\
/\phantom{.................}\\
\ce{CH3}\phantom{.....................}
\end{array}\]
    (f) \[\begin{array}{cc}
\ce{CH3}\phantom{.....................}\\
\backslash\phantom{.................}\\
\ce{CH-I + CH3OH}\\
/\phantom{.................}\\
\ce{CH3}\phantom{.....................}
\end{array}\]
    (g) \[\begin{array}{cc}
\ce{CH3}\phantom{....}\\
|\phantom{.......}\\
\ce{CH3-C-OH + CH3I}\\
|\phantom{.......}\\
\ce{CH3}\phantom{....}
\end{array}\]

Assertion: Addition reaction of water to but-1-ene in acidic medium yields butan-1-ol.

Reason: Addition of water in acidic medium proceeds through the formation of primary carbocation.


Assertion: IUPAC name of the compound

\[\begin{array}{cc}
\ce{CH3 - CH - O - CH2 - CH2 - CH3}\\  
|\phantom{....................}\\
\ce{CH3}\phantom{.................}
\end{array}\] is 2-Ethoxy-2-methylethane.

Reason: In IUPAC nomenclature, ether is regarded as hydrocarbon derivative in which a hydrogen atom is replaced by —OR or —OAr group [where R = alkyl group and Ar = aryl group]


Write complete reaction for the bromination of phenol in aqueous and non-aqueous medium.


How can phenol be converted to aspirin?


Write the IUPAC name of the following compound.


Convert the following:

Ethyl alcohol into ethyl acetate.


Write a chemical reaction for the following conversion:

Acetic acid into ethyl alcohol.


How are the following conversions carried out?

Methyl magnesium bromide→2-Methylpropan-2-ol.


Write IUPAC name of the following compound:

\[\begin{array}{cc}
\phantom{................}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3}\phantom{..}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]


Draw structure of the following compound.

2-Methoxypropane


Draw structure of the following compound.

Prop-2-en-1-ol


Give the structures of Thiosulphuric acid and Peroxy monosulphuric acid.


Write structural formulae for:

p-Nitrophenol


Write structural formulae for:

Salicylic acid


Write the IUPAC name of the following compound:

\[\begin{array}{cc}
\phantom{..............}\ce{CH3}\\
\phantom{............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{.....}|\phantom{......}|\\
\phantom{...}\ce{CH3}\phantom{.}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]


Write the IUPAC name.

\[\begin{array}{cc}
\phantom{................}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C  -CH3}\\
\phantom{.}|\phantom{......}|\phantom{......}|\\
\phantom{....}\ce{CH3\phantom{...}\ce{OH}\phantom{...}\ce{CH3}}\
\end{array}\]


Write IUPAC names of the following compounds: 

\[\begin{array}{cc}
\phantom{...............}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3\phantom{...}OH\phantom{...}CH3}\\
\end{array}\] 


Write the IUPAC name of the following compound:

\[\begin{array}{cc}
\phantom{...............}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3}\phantom{..}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]


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