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प्रश्न
What is metamerism?
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उत्तर १
The ethers with the same molecular formula but different alkyl groups attached on either side of the oxygen atom are called metamers of each other, and the phenomenon is called metamerism
उत्तर २
Metamerism (positional isomerism): Ethers having same molecular formula but different alkyl groups attached on either side of the oxygen atom are called metamers of each other. This phenomenon is called metamerism (positional isomerism).
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संबंधित प्रश्न
Write the IUPAC name of the given compound:
Name the following compound according to the IUPAC system.
\[\begin{array}{cc}
\phantom{.....................................}\ce{CH2OH}\\
\phantom{............................}|\\
\ce{CH3 - CH - CH2 - CH - CH - CH3}\\
|\phantom{....................}|\phantom{............}\\
\ce{CH3}\phantom{..............}\ce{OH}\phantom{.........}\\
\end{array}\]
Name the following compound according to the IUPAC system.
\[\begin{array}{cc}
\ce{H2C = CH - CH - CH2 - CH2 - CH3}\\
|\phantom{...............}\\
\ce{OH}\phantom{............}
\end{array}\]
- Draw the structures of all isomeric alcohols of molecular formula C5H12O and give their IUPAC names.
- Classify the isomers of alcohols in the above question as primary, secondary and tertiary alcohols.
How is phenol converted into the following?
benzoquinone
How is phenol converted into the following?
picric acid
Write the structures of the products when Butan-2-ol reacts with CrO3
Write the structures of the products when Butan-2-ol reacts with SOCl2
Write the IUPAC name of the following :
How do you convert the Ethanal to Propanone
Write structural formula for pentane-1,4-diol.
n-Propyl alcohol and isopropyl alcohol can be chemically distinguished by which reagent?
\[\ce{HC ≡ CH ->[HgSO4][H2SO4] ->[CH3MgBr][H2O] ->[PBr3]}\]
The product of acid catalysed hydration of 2-phenylpropene is:
What happens when benzene diazonium chloride is heated with water?
Explain why p-nitrophenol is more acidic than phenol.
Match the structures of the compounds given in Column I with the name of the compounds given in Column II.
| Column I | Column II | |
| (i) |  |
(a) Hydroquinone |
| (ii) |  |
(b) Phenetole |
| (iii) |  |
(c) Catechol |
| (iv) |  |
(d) o-Cresol |
| (v) |  |
(e) guinone |
| (vi) |  |
(f) Resorcinol |
| (g) Anisole |
Match the starting materials given in Column I with the products formed by these (Column II) in the reaction with HI.
| Column I | Column II | ||
| (i) | CH3—O—CH3 | (a) |  |
| (ii) | \[\begin{array}{cc} \ce{CH3}\phantom{..................}\\ \backslash\phantom{.............}\\ \ce{CH-O-CH3}\\ /\phantom{..............}\\ \ce{CH3}\phantom{..................} \end{array}\] |
(b) | \[\begin{array}{cc} \ce{CH3}\phantom{....}\\ |\phantom{.......}\\ \ce{CH3-C-I + CH3OH}\\ |\phantom{.......}\\ \ce{CH3}\phantom{....} \end{array}\] |
| (iii) | \[\begin{array}{cc} \ce{CH3}\phantom{.}\\ |\phantom{....}\\ \ce{H3C-C-O-CH3}\\ |\phantom{....}\\ \ce{CH3}\phantom{..} \end{array}\] |
(c) |  |
| (iv) |  |
(d) | CH3—OH + CH3—I |
| (e) | \[\begin{array}{cc} \ce{CH3}\phantom{.....................}\\ \backslash\phantom{.................}\\ \ce{CH-OH + CH3I}\\ /\phantom{.................}\\ \ce{CH3}\phantom{.....................} \end{array}\] |
||
| (f) | \[\begin{array}{cc} \ce{CH3}\phantom{.....................}\\ \backslash\phantom{.................}\\ \ce{CH-I + CH3OH}\\ /\phantom{.................}\\ \ce{CH3}\phantom{.....................} \end{array}\] |
||
| (g) | \[\begin{array}{cc} \ce{CH3}\phantom{....}\\ |\phantom{.......}\\ \ce{CH3-C-OH + CH3I}\\ |\phantom{.......}\\ \ce{CH3}\phantom{....} \end{array}\] |
Assertion: IUPAC name of the compound
\[\begin{array}{cc}
\ce{CH3 - CH - O - CH2 - CH2 - CH3}\\
|\phantom{....................}\\
\ce{CH3}\phantom{.................}
\end{array}\] is 2-Ethoxy-2-methylethane.
Reason: In IUPAC nomenclature, ether is regarded as hydrocarbon derivative in which a hydrogen atom is replaced by —OR or —OAr group [where R = alkyl group and Ar = aryl group]
Assertion: Like bromination of benzene, bromination of phenol is also carried out in the presence of Lewis acid.
Reason: Lewis acid polarises the bromine molecule.
Assertion: Phenols give o- and p-nitrophenol on nitration with conc. \[\ce{HNO3}\] and \[\ce{H2SO4}\] mixture.
Reason: –OH group in phenol is o–, p– directing.
Explain why Lewis acid is not required in bromination of phenol?
Write the IUPAC name of the following compound.
Convert the following:
Ethyl alcohol into ethyl acetate.
Write a chemical reaction for the following conversion:
Acetic acid into ethyl alcohol.
How are the following conversions carried out?
Methyl magnesium bromide→2-Methylpropan-2-ol.
Write IUPAC name of the following compound:
\[\begin{array}{cc}
\phantom{................}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3}\phantom{..}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]
Draw structure of the following compound.
2. 5-Diethylphenol
Write the IUPAC name of the following compound:
\[\begin{array}{cc}
\phantom{..............}\ce{CH3}\\
\phantom{............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{.....}|\phantom{......}|\\
\phantom{...}\ce{CH3}\phantom{.}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]
