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Which of the Following Compounds is Not Prepared by the Action of Alcoholic Ni3 on Alkyl Halide - Chemistry

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प्रश्न

Which of the following compounds is NOT prepared by the action of alcoholic NI3 on alkyl halide?

(a) CH3NH2

(b) CH3- CH2- NH2

(c) CH3 - CH2 - CH2 - NH2

(d) (CH3)C- NH2

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उत्तर

(CH3)3C – NH2

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2015-2016 (July)

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संबंधित प्रश्न

What is metamerism? 


Explain metamerism with suitable examples of ethers


Write the IUPAC name of the given compound:


Name the following compound according to IUPAC system.

\[\begin{array}{cc}
\phantom{........................}\ce{CH2OH}\\
\phantom{..................}|\\
\ce{CH3 - CH - CH2 - CH - CH - CH3}\\
\phantom{}|\phantom{.............}|\phantom{........}\\
\phantom{..}\ce{CH3}\phantom{..........}\ce{OH}\phantom{........}
\end{array}\]


Name the following compound according to IUPAC system.

\[\begin{array}{cc}
\ce{CH3 - C = C - CH2OH}\\
\phantom{}|\phantom{....}|\phantom{....}\\
\phantom{}\ce{CH3}\phantom{.}\ce{Br}\phantom{...}
\end{array}\]


Write IUPAC name of the following compound:

\[\begin{array}{cc}
\phantom{................}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3\phantom{.}}\phantom{..}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]


Write IUPAC name of the following compound:

\[\begin{array}{cc}
\ce{CH3 - CH - CH - CH3}\\
|\phantom{......}|\phantom{..}\\
\ce{OH}\phantom{...}\ce{OH}\phantom{}
\end{array}\]


Write IUPAC name of the following compound:

\[\begin{array}{cc}
\ce{HO - CH2 - CH - CH2 - OH}\\
|\phantom{..}\\
\ce{OH}
\end{array}\]


Write IUPAC name of the following compound:


Write IUPAC name of the following compound:


Write IUPAC name of the following compound:


Write IUPAC name of the following compound:

\[\begin{array}{cc}
\ce{CH3 - O - CH2 - CH - CH3}\\
\phantom{..........}|\\
\phantom{............}\ce{CH3}
\end{array}\]


Write IUPAC name of the following compound:

C6H5 – O – C2H5


Write structures of the compounds whose IUPAC names are as follows:

3-Chloromethylpentan-1-ol.


  1. Draw the structures of all isomeric alcohols of molecular formula C5H12O and give their IUPAC names.
  2. Classify the isomers of alcohols in the above question as primary, secondary and tertiary alcohols.

Give IUPAC name of the following ether:

CH3CH2CH2OCH3


Give IUPAC name of the following ether:


Ethylidene dichloride when boiled with aqueous solution of NaOH yields _______.

(A) formaldehyde

(B) acetaldehyde

(C) acetone

(D) ethyl methyl ketone


Write the structure and IUPAC name of 'methyl-n-propyl ether'.


What is the action of hot HI on it?


How is phenol converted into the following?

Benzene


How is phenol converted into the following?

benzoquinone


How is phenol converted into the following?

picric acid


Write IUPAC name of the following compound (CH3)2 N − CH2CH3


Write the IUPAC name of the following compound: 


Write the structures of the products when Butan-2-ol reacts with CrO3


Write the structures of the products when Butan-2-ol reacts with SOCl2


How do you convert the Ethanal to Propanone


What.will be the product fonned when chlorobenzene is heated with sodium metal in the presence of dry ether?


Write structural formula for Methyl vinyl ether.


Write structural formulae for 1-Ethylcyclohexanol.


Write structural formula for pentane-1,4-diol.


Write structural formulae for Cyclohex-2-en-1-ol.


Write IUPAC name of the following

\[\begin{array}{cc}\ce{CH3-CH-CH-CH2-OH}\\|\phantom{.....}|\phantom{.......}\\\ce{OH}\phantom{..}\ce{CH3}\phantom{.....}\end{array}\]


Glycerol is ____________.


Isopropyl alcohol on oxidation forms:


Give IUPAC names of the following compound:


3-methylphenol is called ____________.


The compound HOCH2 – CH2OH is __________.


Ethyl alcohol is industrially prepared from ethylene by:


Which of the following compounds is oxidised to prepare methyl ethyl ketone?


n-Propyl alcohol and isopropyl alcohol can be chemically distinguished by which reagent?


IUPAC name of m-cresol is ____________.


When ethyl alcohol reacts with acetic acid, the products formed are:


1-Propanol and 2-propanol can be best distinguished by:


Which of the following is most acidic?


The IUPAC name of the ether CH2 = CH–CH2OCH3 is:


\[\ce{HC ≡ CH ->[HgSO4][H2SO4] ->[CH3MgBr][H2O] ->[PBr3]}\]


The heating of phenyl methyl ether with HI produces:


Which of the following gives a positive iodoform test?


Among the following sets of reactants which one produces anisole?


IUPAC name of the compound is:

\[\begin{array}{cc}
\ce{CH3-CH-OCH3}\\
|\phantom{....}\\
\ce{CH3}\phantom{..}
\end{array}\]


The correct acidic strength order of the following is:


     (I)


    (II)


     (III)


Give IUPAC name of the compound given below.

\[\begin{array}{cc}
\phantom{}\ce{CH3 - CH - CH2 - CH2 - CH - CH3}\phantom{.}\\
\phantom{.........}|\phantom{...................}|\phantom{...........}\\
\phantom{..}\ce{Cl}\phantom{.................}\ce{OH}\phantom{..}
\end{array}\]


Write the IUPAC name of the compound given below.

\[\begin{array}{cc}
\phantom{}\ce{CH3 - CH2 - C = C - OH}\\
\phantom{........}|\phantom{....}|\phantom{}\\
\phantom{..............}\ce{CH3 CH2OH}
\end{array}\]


What happens when benzene diazonium chloride is heated with water?


Arrange the following compounds in decreasing order of acidity.

\[\ce{H2O, ROH, HC ≡ CH}\]


Write steps to carry out the conversion of phenol to aspirin.


Match the starting materials given in Column I with the products formed by these (Column II) in the reaction with HI.

  Column I   Column II
(i) CH3—O—CH3 (a)
(ii) \[\begin{array}{cc}
\ce{CH3}\phantom{..................}\\
\backslash\phantom{.............}\\
\ce{CH-O-CH3}\\
/\phantom{..............}\\
\ce{CH3}\phantom{..................}
\end{array}\]
(b) \[\begin{array}{cc}
\ce{CH3}\phantom{....}\\
|\phantom{.......}\\
\ce{CH3-C-I + CH3OH}\\
|\phantom{.......}\\
\ce{CH3}\phantom{....}
\end{array}\]
(iii) \[\begin{array}{cc}
\ce{CH3}\phantom{.}\\
|\phantom{....}\\
\ce{H3C-C-O-CH3}\\
|\phantom{....}\\
\ce{CH3}\phantom{..}
\end{array}\]
(c)
(iv) (d) CH3—OH + CH3—I
    (e) \[\begin{array}{cc}
\ce{CH3}\phantom{.....................}\\
\backslash\phantom{.................}\\
\ce{CH-OH + CH3I}\\
/\phantom{.................}\\
\ce{CH3}\phantom{.....................}
\end{array}\]
    (f) \[\begin{array}{cc}
\ce{CH3}\phantom{.....................}\\
\backslash\phantom{.................}\\
\ce{CH-I + CH3OH}\\
/\phantom{.................}\\
\ce{CH3}\phantom{.....................}
\end{array}\]
    (g) \[\begin{array}{cc}
\ce{CH3}\phantom{....}\\
|\phantom{.......}\\
\ce{CH3-C-OH + CH3I}\\
|\phantom{.......}\\
\ce{CH3}\phantom{....}
\end{array}\]

Assertion: Addition reaction of water to but-1-ene in acidic medium yields butan-1-ol.

Reason: Addition of water in acidic medium proceeds through the formation of primary carbocation.


Assertion: p-nitrophenol is more acidic than phenol.

Reason: Nitro group helps in the stabilisation of the phenoxide ion by dispersal of negative charge due to resonance.


Assertion: Like bromination of benzene, bromination of phenol is also carried out in the presence of Lewis acid.

Reason: Lewis acid polarises the bromine molecule.


Assertion: Phenols give o- and p-nitrophenol on nitration with conc. \[\ce{HNO3}\] and \[\ce{H2SO4}\] mixture.

Reason: –OH group in phenol is o–, p– directing.


Write complete reaction for the bromination of phenol in aqueous and non-aqueous medium.


Explain why Lewis acid is not required in bromination of phenol?


Write the IUPAC name of the following compound.


Write a chemical reaction for the following conversion:

Acetic acid into ethyl alcohol.


Identify A and B in the following:


Write IUPAC name of the following compound:

\[\begin{array}{cc}
\phantom{................}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3}\phantom{..}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]


Draw structure of the following compound.

2. 5-Diethylphenol


Draw structure of the following compound.

Prop-2-en-1-ol


Write structural formulae for:

Salicylic acid


The IUPAC name of is ______.


Write the IUPAC name of the following compound:

\[\begin{array}{cc}
\phantom{..............}\ce{CH3}\\
\phantom{............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{.....}|\phantom{......}|\\
\phantom{...}\ce{CH3}\phantom{.}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]


Write the IUPAC name.

\[\begin{array}{cc}
\phantom{................}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C  -CH3}\\
\phantom{.}|\phantom{......}|\phantom{......}|\\
\phantom{....}\ce{CH3\phantom{...}\ce{OH}\phantom{...}\ce{CH3}}\
\end{array}\]


Write IUPAC names of the following compounds: 

\[\begin{array}{cc}
\phantom{...............}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3\phantom{...}OH\phantom{...}CH3}\\
\end{array}\] 


Write the IUPAC name of the following compound:

\[\begin{array}{cc}
\phantom{...............}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3}\phantom{..}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]


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