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प्रश्न
Explain metamerism with suitable examples of ethers
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उत्तर
The property in which ethers have same molecular formula but different alkyl groups in their structures is called metamerism and the isomers obtained are called as metamers.
Examples :
e.g. C2H5 - O - C2H5 - Diethyl ether;
CH3 - O - C3H7 - Methyl n-propyl ether
In the above example both ethers are having same molecular formula i.e. C4H10 but different alkyl groups in their structure, so they are metamers of each other.
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संबंधित प्रश्न
Name the following compound according to the IUPAC system.
\[\begin{array}{cc}
\ce{CH3 - C = C - CH2OH}\\
|\phantom{......}|\phantom{.....}\\
\ce{CH3}\phantom{.}\ce{Br}\phantom{....}\\
\end{array}\]
Write the IUPAC name of the following compound:
Write the IUPAC name of the following compound:
\[\begin{array}{cc}
\ce{CH3 - O - CH2 - CH - CH3}\\
\phantom{................}|\\
\phantom{....................}\ce{CH3}
\end{array}\]
Write the IUPAC name of the following compound:
\[\begin{array}{cc}
\ce{CH3 - CH2 - O - CH - CH2 - CH3}\\
\phantom{....}|\\
\phantom{........}\ce{CH3}
\end{array}\]
- Draw the structures of all isomeric alcohols of molecular formula C5H12O and give their IUPAC names.
- Classify the isomers of alcohols in the above question as primary, secondary and tertiary alcohols.
Give the IUPAC name of the following ether:
Give the IUPAC name of the following ether:
What is the action of hot HI on it?
How is phenol converted into the following?
picric acid
Write IUPAC name of the following compound (CH3)2 N − CH2CH3
Write the IUPAC name of the following compound:
Write the structures of the products when Butan-2-ol reacts with SOCl2
Propanoic acid to ethylamine.
HBr reacts fastest with ____________.
The major product formed by the reaction:
\[\begin{array}{cc}
\ce{CH3CH-CH2Br ->[CH3O^-][CH3OH] is}\\
|\phantom{................}\\
\ce{CH3}\phantom{.............}
\end{array}\]
The heating of phenyl methyl ether with HI produces:
\[\ce{Phenol ->[Zn, dust] 'X' ->[CH3Cl][Anhy. AlCl3] 'Y' ->[Alkaline][KMnO4] 'Z'}\]
The product ‘Z’ is:
IUPAC name of the compound is:
\[\begin{array}{cc}
\ce{CH3-CH-OCH3}\\
|\phantom{....}\\
\ce{CH3}\phantom{..}
\end{array}\]
The correct acidic strength order of the following is:
(I)
(II)
(III)
Write the IUPAC name of the compound given below.
\[\begin{array}{cc}
\phantom{}\ce{CH3 - CH2 - C = C - OH}\\
\phantom{........}|\phantom{....}|\phantom{}\\
\phantom{..............}\ce{CH3 CH2OH}
\end{array}\]
Match the structures of the compounds given in Column I with the name of the compounds given in Column II.
| Column I | Column II | |
| (i) |  |
(a) Hydroquinone |
| (ii) |  |
(b) Phenetole |
| (iii) |  |
(c) Catechol |
| (iv) |  |
(d) o-Cresol |
| (v) |  |
(e) guinone |
| (vi) |  |
(f) Resorcinol |
| (g) Anisole |
Assertion: IUPAC name of the compound
\[\begin{array}{cc}
\ce{CH3 - CH - O - CH2 - CH2 - CH3}\\
|\phantom{....................}\\
\ce{CH3}\phantom{.................}
\end{array}\] is 2-Ethoxy-2-methylethane.
Reason: In IUPAC nomenclature, ether is regarded as hydrocarbon derivative in which a hydrogen atom is replaced by —OR or —OAr group [where R = alkyl group and Ar = aryl group]
Write complete reaction for the bromination of phenol in aqueous and non-aqueous medium.
Write a chemical reaction for the following conversion:
Acetic acid into ethyl alcohol.
Write structural formulae for:
p-Nitrophenol
Write IUPAC name of the following compound:
\[\begin{array}{cc}
\phantom{...............}\ce{CH3}\\
\phantom{............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3}\phantom{...}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]
