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How is Phenol Converted into the Following? Picric Acid

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प्रश्न

How is phenol converted into the following?

picric acid

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उत्तर

Conversion of phenol into picric acid:

When phenol is treated with hot and conc. HNO3 in the presence of conc. H2SO4 (nitrating mixture), yellow coloured picric acid, i.e. 2,4,6-Trinitrophenol is obtained

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2012-2013 (October)

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\[\begin{array}{cc}
\phantom{.....................................}\ce{CH2OH}\\
\phantom{............................}|\\
\ce{CH3 - CH - CH2 - CH - CH - CH3}\\
|\phantom{....................}|\phantom{............}\\
\ce{CH3}\phantom{..............}\ce{OH}\phantom{.........}\\
\end{array}\]


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\[\begin{array}{cc}
\ce{H3C - CH - CH2 - CH - CH - CH2 - CH3}\\
|\phantom{....................}|\phantom{.........}|\phantom{.............}\\
\ce{OH}\phantom{................}\ce{OH}\phantom{...}\ce{C{_2}H5}\phantom{.........}\\
\end{array}\]


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\[\begin{array}{cc}
\ce{CH3 - O - CH2 - CH - CH3}\\
\phantom{................}|\\
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\[\begin{array}{cc}
\ce{CH3 - CH2 - O - CH - CH2 - CH3}\\
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\phantom{...............}\ce{CH3}\\
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\phantom{................}\ce{CH3}\\
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\phantom{...............}\ce{CH3}\\
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\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
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