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Science (English Medium) Class 12 - CBSE Question Bank Solutions for Chemistry

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Chemistry
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Mark the correct increasing order of reactivity of the following compounds with HBr/HCl.

(a)
(b)
(c)
[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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Name the factors responsible for the solubility of alcohols in water.

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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Suggest a reagent for the following conversion.

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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Alcohols react with active metals e.g. Na, K etc. to give corresponding alkoxides. Write down the decreasing order of reactivity of sodium metal towards primary, secondary and tertiary alcohols.

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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Explain why is OH group in phenols more strongly held as compared to OH group in alcohols.

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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Explain why nucleophilic substitution reactions are not very common in phenols.

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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In Kolbe’s reaction, instead of phenol, phenoxide ion is treated with carbon dioxide. Why?

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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Ethers can be prepared by Williamson synthesis in which an alkyl halide is reacted with sodium alkoxide. Di-tert-butyl ether can’t be prepared by this method. Explain.

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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Why is the C – O – H bond angle in alcohols slightly less than the tetrahedral angle whereas the C – O – C bond angle in ether is slightly greater?

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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Assertion: Bond angle in ethers is slightly less than the tetrahedral angle.

Reason: There is a repulsion between the two bulky (–R) groups.

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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The gas evolved when methylamine reacts with nitrous acid is:

[9] Amines
Chapter: [9] Amines
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Acid anhydrides on reaction with primary amines give ______.

[9] Amines
Chapter: [9] Amines
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Carbohydrates are essential for life in both plants and animals. Name the carbohydrates that are used as storage molecules in plants and animals, also name the carbohydrate which is present in wood or in the fibre of cotton cloth.

[10] Biomolecules
Chapter: [10] Biomolecules
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Which of the following are example of synthetic rubber?

(i) Polychloroprene

(ii) Polyacrylonitrile

(iii) Buna-N

(iv) cis-polyisoprene

[15] Polymers
Chapter: [15] Polymers
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Vulcanisation makes rubber:

(i) more elastic

(ii) soluble in inorganic solvent

(iii) crystalline

(iv) more stiff

[15] Polymers
Chapter: [15] Polymers
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Identify the polymer given below:

[15] Polymers
Chapter: [15] Polymers
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Match materials given in Column I with the polymers given in Column II.

Column I Column II
(i) Natural rubber latex (a) Nylon
(ii) Wood laminates (b) Neoprene
(iii) Ropes and fibres (c) Dacron
(iv) Polyester fabric (d) Melamine formaldehyde resins
(v) Synthetic rubber (e) Urea-formaldehyde resins
(vi) Unbreakable crockery (f) cis-polyisoprene
[15] Polymers
Chapter: [15] Polymers
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Solutions of two electrolytes ‘A’ and ‘B’ are diluted. The Λm of ‘B’ increases 1.5 times while that of A increases 25 times. Which of the two is a strong electrolyte? Justify your answer. Graphically show the behavior of ‘A’ and ‘B’.

[2] Electrochemistry
Chapter: [2] Electrochemistry
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The molar conductivity of CH3COOH at infinite dilution is 390 Scm2/mol. Using the graph and given information, the molar conductivity of CH3COOK will be:

[2] Electrochemistry
Chapter: [2] Electrochemistry
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Which of the following statements is not correct for amines?

[9] Amines
Chapter: [9] Amines
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