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Science (English Medium) Class 12 - CBSE Important Questions for Chemistry

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 Write a condition under which a bimolecular reaction is kinetically first order. Give an example of  such a reaction. (Given : log2 = 0.3010,log 3 = 0.4771, log5 = 0.6990).

Appears in 1 question paper
Chapter: [3] Chemical Kinetics
Concept: Temperature Dependence of the Rate of a Reaction

 Predict the main product of the following reactions:

Appears in 1 question paper
Chapter: [3] Chemical Kinetics
Concept: Temperature Dependence of the Rate of a Reaction

Read the passage given below and answer the following question.

Are there nuclear reactions going on in our bodies?

There are nuclear reactions constantly occurring in our bodies, but there are very few of them compared to the chemical reactions, and they do not affect our bodies much. All of the physical processes that take place to keep a human body running are chemical processes. Nuclear reactions can lead to chemical damage, which the body may notice and try to fix. The nuclear reaction occurring in our bodies is radioactive decay. This is the change of a less stable nucleus to a more stable nucleus. Every atom has either a stable nucleus or an unstable nucleus, depending on how big it is and on the ratio of protons to neutrons. The ratio of neutrons to protons in a stable nucleus is thus around 1 : 1 for small nuclei (Z < 20). Nuclei with too many neutrons, too few neutrons, or that are simply too big are unstable. They eventually transform to a stable form through radioactive decay. Wherever there are atoms with unstable nuclei (radioactive atoms), there are nuclear reactions occurring naturally. The interesting thing is that there are small amounts of radioactive atoms everywhere: in your chair, in the ground, in the food you eat, and yes, in your body.

The most common natural radioactive isotopes in humans are carbon-14 and potassium-40. Chemically, these isotopes behave exactly like stable carbon and potassium. For this reason, the body uses carbon-14 and potassium-40 just like it does normal carbon and potassium; building them into the different parts of the cells, without knowing that they are radioactive. In time, carbon-14 atoms decay to stable nitrogen atoms and potassium-40 atoms decay to stable calcium atoms. Chemicals in the body that relied on having a carbon-14 atom or potassium-40 atom in a certain spot will suddenly have a nitrogen or calcium atom. Such a change damages the chemical. Normally, such changes are so rare, that the body can repair the damage or filter away the damaged chemicals.

The natural occurrence of carbon-14 decay in the body is the core principle behind carbon dating. As long as a person is alive and still eating, every carbon-14 atom that decays into a nitrogen atom is replaced on average with a new carbon-14 atom. But once a person dies, he stops replacing the decaying carbon-14 atoms. Slowly the carbon-14 atoms decay to nitrogen without being replaced, so that there is less and less carbon-14 in a dead body. The rate at which carbon-14 decays is constant and follows first order kinetics. It has a half-life of nearly 6000 years, so by measuring the relative amount of carbon-14 in a bone, archeologists can calculate when the person died. All living organisms consume carbon, so carbon dating can be used to date any living organism, and any object made from a living organism. Bones, wood, leather, and even paper can be accurately dated, as long as they first existed within the last 60,000 years. This is all because of the fact that nuclear reactions naturally occur in living organisms.

Suppose an organism has 20 g of Carbon-14 at its time of death. Approximately how much Carbon-14 remains after 10,320 years? (Given antilog 0.517 = 3.289)

Appears in 1 question paper
Chapter: [3] Chemical Kinetics
Concept: Half Life Period of a Reaction

Read the passage given below and answer the following question.

Are there nuclear reactions going on in our bodies?

There are nuclear reactions constantly occurring in our bodies, but there are very few of them compared to the chemical reactions, and they do not affect our bodies much. All of the physical processes that take place to keep a human body running are chemical processes. Nuclear reactions can lead to chemical damage, which the body may notice and try to fix. The nuclear reaction occurring in our bodies is radioactive decay. This is the change of a less stable nucleus to a more stable nucleus. Every atom has either a stable nucleus or an unstable nucleus, depending on how big it is and on the ratio of protons to neutrons. The ratio of neutrons to protons in a stable nucleus is thus around 1 : 1 for small nuclei (Z < 20). Nuclei with too many neutrons, too few neutrons, or that are simply too big are unstable. They eventually transform to a stable form through radioactive decay. Wherever there are atoms with unstable nuclei (radioactive atoms), there are nuclear reactions occurring naturally. The interesting thing is that there are small amounts of radioactive atoms everywhere: in your chair, in the ground, in the food you eat, and yes, in your body.

The most common natural radioactive isotopes in humans are carbon-14 and potassium-40. Chemically, these isotopes behave exactly like stable carbon and potassium. For this reason, the body uses carbon-14 and potassium-40 just like it does normal carbon and potassium; building them into the different parts of the cells, without knowing that they are radioactive. In time, carbon-14 atoms decay to stable nitrogen atoms and potassium-40 atoms decay to stable calcium atoms. Chemicals in the body that relied on having a carbon-14 atom or potassium-40 atom in a certain spot will suddenly have a nitrogen or calcium atom. Such a change damages the chemical. Normally, such changes are so rare, that the body can repair the damage or filter away the damaged chemicals.

The natural occurrence of carbon-14 decay in the body is the core principle behind carbon dating. As long as a person is alive and still eating, every carbon-14 atom that decays into a nitrogen atom is replaced on average with a new carbon-14 atom. But once a person dies, he stops replacing the decaying carbon-14 atoms. Slowly the carbon-14 atoms decay to nitrogen without being replaced, so that there is less and less carbon-14 in a dead body. The rate at which carbon-14 decays is constant and follows first order kinetics. It has a half-life of nearly 6000 years, so by measuring the relative amount of carbon-14 in a bone, archeologists can calculate when the person died. All living organisms consume carbon, so carbon dating can be used to date any living organism, and any object made from a living organism. Bones, wood, leather, and even paper can be accurately dated, as long as they first existed within the last 60,000 years. This is all because of the fact that nuclear reactions naturally occur in living organisms.

Approximately how old is a fossil with 12 g of Carbon-14 if it initially possessed 32 g of Carbon-14? (Given log 2.667 = 0.4260)

Appears in 1 question paper
Chapter: [3] Chemical Kinetics
Concept: Half Life Period of a Reaction

Which radioactive isotope would have the longer half-life 15O or 19O? (Given rate constants for 15O and 19O are 5.63 × 10–3 s–1 and k = 2.38 × 10–2 s–1 respectively.)

Appears in 1 question paper
Chapter: [3] Chemical Kinetics
Concept: Half Life Period of a Reaction

For the reaction, \[\ce{A +2B → AB2}\], the order w.r.t. reactant A is 2 and w.r.t. reactant B. What will be change in rate of reaction if the concentration of A is doubled and B is halved?

Appears in 1 question paper
Chapter: [3] Chemical Kinetics
Concept: Factors Influencing Rate of a Reaction

Arrhenius equation can be represented graphically as follows:

The (i) intercept and (ii) slope of the graph are:

Appears in 1 question paper
Chapter: [3] Chemical Kinetics
Concept: Temperature Dependence of the Rate of a Reaction

A first-order reaction takes 69.3 min for 50% completion. What is the time needed for 80% of the reaction to get completed? (Given: log 5 = 0.6990, log 8 = 0.9030, log 2 = 0.3010)

Appears in 1 question paper
Chapter: [3] Chemical Kinetics
Concept: Half Life Period of a Reaction

Explain how and why will the rate of reaction for a given reaction be affected when a catalyst is added.

Appears in 1 question paper
Chapter: [3] Chemical Kinetics
Concept: Effect of Catalyst on the Rate of Reaction

Explain how and why will the rate of reaction for a given reaction be affected when the temperature at which the reaction was taking place is decreased.

Appears in 1 question paper
Chapter: [3] Chemical Kinetics
Concept: Temperature Dependence of the Rate of a Reaction

The slope in the plot of ln[R] vs. time for a first order reaction is ______.

Appears in 1 question paper
Chapter: [3] Chemical Kinetics
Concept: First Order Reactions

For the reaction 3A `rightarrow` 2B, rate of reaction `+ (d[B])/(dt)` is equal to ______.

Appears in 1 question paper
Chapter: [3] Chemical Kinetics
Concept: Effect of Catalyst on the Rate of Reaction

The slope in the plot of [R] Vs. time for a zero-order reaction is ______.

Appears in 1 question paper
Chapter: [3] Chemical Kinetics
Concept: Zero Order Reactions

The slope in the plot of `log  ["R"]_0/(["R"])` Vs. time for a first-order reaction is ______.

Appears in 1 question paper
Chapter: [3] Chemical Kinetics
Concept: First Order Reactions

For the reaction \[\ce{3A -> 2B}\], rate of reaction `-("d"["A"])/"dt"` is equal to ______.

Appears in 1 question paper
Chapter: [3] Chemical Kinetics
Concept: Effect of Catalyst on the Rate of Reaction

Assertion (A): For a zero-order reaction, the unit of rate constant and rate of reaction are same.

Reason (R): Rate of reaction for zero order reaction is independent of concentration of reactant.

Appears in 1 question paper
Chapter: [3] Chemical Kinetics
Concept: Zero Order Reactions

Assertion (A): The half-life of a reaction is the time in which the concentration of the reactant is reduced to one-half of its initial concentration.

Reason (R): In first-order kinetics, when the concentration of reactant is doubled, its half-life is doubled.

Appears in 1 question paper
Chapter: [3] Chemical Kinetics
Concept: Half Life Period of a Reaction

Assertion (A): Order of reaction is applicable to elementary as well as complex reactions.

Reason (R): For a complex reaction, molecularity has no meaning.

Appears in 1 question paper
Chapter: [3] Chemical Kinetics
Concept: Factors Influencing Rate of a Reaction

Which of the following statement is true?

Appears in 1 question paper
Chapter: [3] Chemical Kinetics
Concept: Factors Influencing Rate of a Reaction

If the initial concentration of substance A is 1.5 M and after 120 seconds the concentration of substance A is 0.75 M, the rate constant for the reaction if it follows zero-order kinetics is ______.

Appears in 1 question paper
Chapter: [3] Chemical Kinetics
Concept: Zero Order Reactions
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