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Write Structures of Compounds a and B of the Following Reaction :

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Question

Write structures of compounds A and B of the following reaction : 

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Solution

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2018-2019 (March) 56/1/1

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RELATED QUESTIONS

How is Benzonitrile converted to Benzophenone?


Write the IUPAC name of the following coordination compound:

[Cr(NH3)4(H2O)2]Cl3


Ligand (en) is an example of ___________.


Which of the following complexes are heteroleptic?

(i) \[\ce{[Cr(NH3)6]^{3+}}\]

(ii) \[\ce{[Fe(NH3)4]Cl2]^+}\]

(iii) \[\ce{[Mn(CN)6]^{4-}}\]

(iv) \[\ce{[Co(NH3)4]Cl2]}\]


A complex of the type \[\ce{[M(AA)2X2]^{n+}}\] is known to be optically active. What does this indicate about the structure of the complex? Give one example of such complex.


Match the complex ions given in Column I with the colours given in Column II and assign the correct code:

Column I (Complex ion) Column II (Colour)
A. \[\ce{[Co(NH3)6]^{3+}}\] 1. Violet
B. \[\ce{[Ti(H2O)6]^{3+}}\] 2. Green
C. \[\ce{[Ni(H2O)6]^{2+}}\] 3. Pale blue
D. \[\ce{(Ni(H2O)4 (en)]^{2+} (aq)}\] 4. Yellowish orange
  5. Blue

Given below are two statements.

Statement I: In CuSO4·5H2O, Cu-O bonds are present.

Statement II: In CuSO4·5H2O, ligands coordinating with Cu(II) ion are O- and S-based ligands.

In light of the above statement, choose the correct answer from the options given below.


Assertion (A): EDTA is a hexadentate ligand.

Reason (R): EDTA has 2 nitrogen and 4 oxygen donor atoms.


Give two examples of unidentate ligands.


Statement I: [Co(NH3)6]3+ is a homoleptic compleх whereas [Co(NH3)4Cl2]+ is a heteroleptic complex.

Statement II: Complex [Co(NH3)6]3+ has only one kind of ligands but [Co(NH3)4Cl2]+ has more than one kind of ligands.

In the light of the above statements, Choose the correct answer form the options given below.


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