English
Karnataka Board PUCPUC Science 2nd PUC Class 12

A complex of the type [M(AA)X2XX2]Xn+ is known to be optically active. What does this indicate about the structure of the complex? Give one example of such complex.

Advertisements
Advertisements

Question

A complex of the type \[\ce{[M(AA)2X2]^{n+}}\] is known to be optically active. What does this indicate about the structure of the complex? Give one example of such complex.

Short/Brief Note
Advertisements

Solution

An optically active \[\ce{[M(AA)2X2]^{n+}}\] indicates civ-octahedral structure e.g. \[\ce{cis-[Pt(en)2Cl2]^{2+}}\] or \[\ce{cis-[Cr(en)2Cl2]^+}\]

shaalaa.com
  Is there an error in this question or solution?
Chapter 9: Coordination Compounds - Exercises [Page 124]

APPEARS IN

NCERT Exemplar Chemistry Exemplar [English] Class 12
Chapter 9 Coordination Compounds
Exercises | Q III. 26. | Page 124

RELATED QUESTIONS

Predict the co-ordination No. of cs+ ion if `r_(Cs)^+` = 1.69Å and `r_(Cl)^-` = 1.81Å.


Write applications of co-ordination compounds in medicine and electroplating.


Write structures of compounds A, B and C in of the following reactions


Write structures of compounds A, B and C in of the following reactions


The ligand triethylenetetramine is _______.


The oxidation number of Fe in K4[Fe(CN)6] is ____________.


The coordination number of the central ion may be obtained from:


Which of the following complexes formed by \[\ce{Cu^2+}\] ions is most stable?


When 0.1 mol \[\ce{CoCl3 (NH3)5}\] is treated with excess of \[\ce{AgNO3}\], 0.2 mol of \[\ce{AgCl}\] are obtained. The conductivity of solution will correspond to ______.


Which of the following complexes are heteroleptic?

(i) \[\ce{[Cr(NH3)6]^{3+}}\]

(ii) \[\ce{[Fe(NH3)4]Cl2]^+}\]

(iii) \[\ce{[Mn(CN)6]^{4-}}\]

(iv) \[\ce{[Co(NH3)4]Cl2]}\]


Identify the correct statements for the behaviour of ethane-1, 2-diamine as a ligand.

(i) It is a neutral ligand.

(ii) It is a didentate ligand.

(iii) It is a chelating ligand.

(iv) It is a unidentate ligand.


Match the complex ions given in Column I with the colours given in Column II and assign the correct code:

Column I (Complex ion) Column II (Colour)
A. \[\ce{[Co(NH3)6]^{3+}}\] 1. Violet
B. \[\ce{[Ti(H2O)6]^{3+}}\] 2. Green
C. \[\ce{[Ni(H2O)6]^{2+}}\] 3. Pale blue
D. \[\ce{(Ni(H2O)4 (en)]^{2+} (aq)}\] 4. Yellowish orange
  5. Blue

Which one of the following does not achieve an octet of electrons in the central atom?


Oxidation number of carbon in CH2Cl2 is


Which of the following is an ionic ligand?


The oxidation number d-arbitral occupation and co-ordination number of Cr in the complex cis [Cr(en)2Cl2]Cl are respectively.


Metal attached with EDTA in an octahedral complex, has coordination number ______.


Which of the following species cannot act as a ligand? Give reason.


Explain with two examples of the following:

Ligand


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×