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Write Structures of Compounds A, B and C in of the Following Reactions - 1

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Question

Write structures of compounds A, B and C in of the following reactions

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Solution

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2016-2017 (March) Delhi Set 3

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Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complex:

K3[Co(C2O4)3]


Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complex:

cis-[CrCl2(en)2]Cl


A complex of the type \[\ce{[M(AA)2X2]^{n+}}\] is known to be optically active. What does this indicate about the structure of the complex? Give one example of such complex.


Match the complex ions given in Column I with the colours given in Column II and assign the correct code:

Column I (Complex ion) Column II (Colour)
A. \[\ce{[Co(NH3)6]^{3+}}\] 1. Violet
B. \[\ce{[Ti(H2O)6]^{3+}}\] 2. Green
C. \[\ce{[Ni(H2O)6]^{2+}}\] 3. Pale blue
D. \[\ce{(Ni(H2O)4 (en)]^{2+} (aq)}\] 4. Yellowish orange
  5. Blue

Match the compounds given in Column I with the oxidation state of cobalt present in it (given in Column II) and assign the correct code:

Column I (Compound) Column II (Oxidation state of Co)
A. \[\ce{[Co(NCS)(NH3)5](SO3)}\] 1. + 4
B. \[\ce{[Co(NH3)4 CL2]SO4}\] 2. 0
C. \[\ce{Na4[Co(S2O3)3]}\] 3. + 1
D. \[\ce{[Co2(CO)8]}\] 4. + 2
  5. + 3

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