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A complex of the type [M(AA)X2XX2]Xn+ is known to be optically active. What does this indicate about the structure of the complex? Give one example of such complex. - Chemistry

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प्रश्न

A complex of the type \[\ce{[M(AA)2X2]^{n+}}\] is known to be optically active. What does this indicate about the structure of the complex? Give one example of such complex.

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उत्तर

An optically active \[\ce{[M(AA)2X2]^{n+}}\] indicates civ-octahedral structure e.g. \[\ce{cis-[Pt(en)2Cl2]^{2+}}\] or \[\ce{cis-[Cr(en)2Cl2]^+}\]

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अध्याय 9: Coordination Compounds - Exercises [पृष्ठ १२४]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
अध्याय 9 Coordination Compounds
Exercises | Q III. 26. | पृष्ठ १२४

संबंधित प्रश्न

Classify the following ligands into monodentate and polydentate —

  1. Ammonia
  2. Carbon monoxide
  3. Ethylene diamine
  4. Ethylene diamine tetra acetate ion

What is meant by unidentate ligand?


What is the coordination entity formed when excess of aqueous KCN is added to an aqueous solution of copper sulphate? Why is it that no precipitate of copper sulphide is obtained when H2S(g) is passed through this solution?


Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complex:

cis-[CrCl2(en)2]Cl


Which of the following compounds is used as a semipermeable membrane?

(a) Potassium ferrocyanide

(b) Potassium argentocyanide

(c) Sodium meta aluminate

(d) Copper ferrocyanide


How is Benzonitrile converted to Benzophenone?


Write the IUPAC name of the following complex:

[Co(NH3)5(CO3)]Cl


When 0.1 mol \[\ce{CoCl3 (NH3)5}\] is treated with excess of \[\ce{AgNO3}\], 0.2 mol of \[\ce{AgCl}\] are obtained. The conductivity of solution will correspond to ______.


When 1 mol \[\ce{CrCl3.6H2O}\] is treated with excess of \[\ce{AgNO3}\], 3 mol of \[\ce{AgCl}\] are obtained. The formula of the complex is ______.


Identify the correct statements for the behaviour of ethane-1, 2-diamine as a ligand.

(i) It is a neutral ligand.

(ii) It is a didentate ligand.

(iii) It is a chelating ligand.

(iv) It is a unidentate ligand.


Match the coordination compounds given in Column I with the central metal atoms given in Column II and assign the correct code:

Column I (Coordination Compound) Column II (Central metal atom)
A. Chlorophyll 1. rhodium
B. Blood pigment 2. cobalt
C. Wilkinson catalyst 3. calcium
D. Vitamin B12 4. iron
  5. magnesium

Which of the following is an ionic ligand?


The oxidation state of Fe in the brown ring complex [F3(H2O)5NO]SO4 is


Which of the following ligands can exhibit linkage isomerism?


What are Heteroleptic complexes?


The correct order of the spin-only magnetic moment of metal ions in the following low spin complexes,

\[\ce{[V(CN)6]^{4-}, [Fe(CN)6]^{4-}, [Ru(NH3)6]^{3+} and [Cr(NH3)6]^2}\] is:


Assertion (A): EDTA is a hexadentate ligand.

Reason (R): EDTA has 2 nitrogen and 4 oxygen donor atoms.


What is meant by the chelate effect? Give an example.


Explain the following, giving two examples:

Coordination number


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