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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Which of the following complexes are homoleptic? (i) [Co(NHX3)X6]X3+ (ii) [Co(NHX3)X4 ClX2]X+ (iii) [Ni(CN)X4]X2− (iv) [Ni(NHX3)X4ClX2]

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प्रश्न

Which of the following complexes are homoleptic?

(i) \[\ce{[Co(NH3)6]^{3+}}\]

(ii) \[\ce{[Co(NH3)4 Cl2]^{+}}\]

(iii) \[\ce{[Ni(CN)4]^{2-}}\]

(iv) \[\ce{[Ni(NH3)4Cl2]}\]

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उत्तर

(i) \[\ce{[Co(NH3)6]^{3+}}\]

(iii) \[\ce{[Ni(CN)4]^{2-}}\]

Explanation:

Complexes in which a metal is bound to only one kind of donor groups, e.g., \[\ce{[Co(NH3)6]^{3+}}\], are known as homoleptic.

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अध्याय 9: Coordination Compounds - Exercises [पृष्ठ १२३]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
अध्याय 9 Coordination Compounds
Exercises | Q II. 19. | पृष्ठ १२३

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Statement I: [Co(NH3)6]3+ is a homoleptic compleх whereas [Co(NH3)4Cl2]+ is a heteroleptic complex.

Statement II: Complex [Co(NH3)6]3+ has only one kind of ligands but [Co(NH3)4Cl2]+ has more than one kind of ligands.

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