Advertisements
Advertisements
प्रश्न
Amongst the following, the most stable complex is:
विकल्प
[Fe(H2O)6]3+
[Fe(NH3)6]3+
[Fe(C2O4)3]3−
[FeCl6]3−
Advertisements
उत्तर
[Fe(C2O4)3]3−
Explanation:
[Fe(C2O4)3]3− is the most stable complex because oxalate ion \[\ce{(C2O^{2-}_4)}\] is a bidentate ligand. Bidentate ligands form chelate rings with the metal ion, which increases the stability of the complex due to the chelate effect. The other ligands (H2O, NH3, Cl−) are monodentate ligands and form comparatively less stable complexes.
APPEARS IN
संबंधित प्रश्न
Write the structure and IUPAC names of all the metamers represented by formula C4H10
Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complex:
cis-[CrCl2(en)2]Cl
Write IUPAC names of the following compounds

How is Benzonitrile converted to Benzophenone?
Complete the following reactions
NH3+3Cl2(excess) ---->
Write the structures of compounds A, B and C in the following reactions:

Which of the following complexes are homoleptic?
(i) \[\ce{[Co(NH3)6]^{3+}}\]
(ii) \[\ce{[Co(NH3)4 Cl2]^{+}}\]
(iii) \[\ce{[Ni(CN)4]^{2-}}\]
(iv) \[\ce{[Ni(NH3)4Cl2]}\]
A coordination compound \[\ce{CrCl3.4H2O}\] precipitates silver chloride when treated with silver nitrate. The molar conductance of its solution corresponds to a total of two ions. Write structural formula of the compound and name it.
A complex of the type \[\ce{[M(AA)2X2]^{n+}}\] is known to be optically active. What does this indicate about the structure of the complex? Give one example of such complex.
Assertion: \[\ce{Cr(H2O)6]Cl2 and [Fe(H2O)6]Cl2}\] are reducing in nature.
Reason: Unpaired electrons are present in their d-orbitals.
Which one of the following does not achieve an octet of electrons in the central atom?
Which of the following is an ionic ligand?
Which of the following ligands can exhibit linkage isomerism?
What are Homoleptic complexes?
Given below are two statements.
Statement I: In CuSO4·5H2O, Cu-O bonds are present.
Statement II: In CuSO4·5H2O, ligands coordinating with Cu(II) ion are O- and S-based ligands.
In light of the above statement, choose the correct answer from the options given below.
The following ligand is:

What is meant by the chelate effect? Give an example.
Explain the following, giving two examples:
Heteroleptic
Give two examples of didentate ligands.
Give two examples of ambidentate ligands.
