English
Karnataka Board PUCPUC Science Class 11

What happens when BF3 is reacted with ammonia? - Chemistry

Advertisements
Advertisements

Question

What happens when BF3 is reacted with ammonia?

Short/Brief Note
Advertisements

Solution

BF3 (a Lewis acid) reacts with NH3 (a Lewis base) to form an adduct. This results in a complete octet around B in BF3

\[\ce{F_3B + :NH_3 -> F_3B <- :NH_3}\]

shaalaa.com
Group 13 Elements - The Boron Family
  Is there an error in this question or solution?

RELATED QUESTIONS

Suggest reasons why the B–F bond lengths in BF3 (130 pm) and `"BF"_4^(-)` (143 pm) differ.


Write a balanced equation for Al + NaOH → ?


Which of the following oxides is acidic in nature?


The exhibition of highest co-ordination number depends on the availability of vacant orbitals in the central atom. Which of the following elements is not likely to act as central atom in \[\ce{MF^{3-}6}\]?


Ionisation enthalpy (∆iH1kJ mol–1) for the elements of Group 13 follows the order.


Explain the following:

Electron gain enthalpy of chlorine is more negative as compared to fluorine.


Explain the following:

Tl (NO3)3 acts as an oxidising agent.


Identify the compounds A, X and Z in the following reactions:

\[\ce{X ->[Δ][370 K] HBO2 ->[Δ][> 370 K] Z}\]


Match the species given in Column I with the properties mentioned in Column II.

Column I Column II
(i) \[\ce{BF^{-}4}\] (a) Oxidation state of central atom is +4
(ii) AICI3 (b) Strong oxidising agent
(iii) SnO (c) Lewis acid
(iv) PbO2 (d) Can be further oxidised
  (e) Tetrahedral shape

Match the species given in Column I with properties given in Column II.

Column I Column II
(i) Diborane (a) Used as a flux for soldering metals
(ii) Galluim (b) Crystalline form of silica
(iii) Borax (c) Banana bonds
(iv) Aluminosilicate (d) Low melting, high boiling, useful for measuring high temperatures
(v) Quartz (e) Used as catalyst in petrochemical industries

Describe the general trends in the following properties of the elements in Groups 13 and 14.

Atomic size


Account for the following observations:

The +1 oxidation state of thallium is more stable than its +3 state.


Three pairs of compounds are given below. Identify that compound in each of the pairs which has group 13 element in more stable oxidation state. Give reason for your choice. State the nature of bonding also.

TlCl3, TlCl


Three pairs of compounds are given below. Identify that compound in each of the pairs which has group 13 element in more stable oxidation state. Give reason for your choice. State the nature of bonding also.

InCl3, InCl


BCl3 exists as monomer whereas AlCl3 is dimerised through halogen bridging. Give reason. Explain the structure of the dimer of AlCl3 also.


A nonmetallic element of group 13, used in making bullet proof vests is extremely hard solid of black colour. It can exist in many allotropic forms and has unusually high melting point. Its trifluoride acts as Lewis acid towards ammonia. The element exihibits maximum covalency of four. Identify the element and write the reaction of its trifluoride with ammonia. Explain why does the trifluoride act as a Lewis acid.


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×