Advertisements
Advertisements
Question
Value of universal gas constant (R) is same for all gases. What is its physical significance?
Advertisements
Solution
Unit of R depends on the units of p, V and T are measured, We know, `R = (pV)/(nT)`
Now, let's say, the pressure is measured in Pascal, per mole volume is measured in m3 and temperature is measured in Kelvin, then. Units of ‘R’ are Pa m3K–1 mol–1. Also, R is work done per mole per kelvin. It’s unit is J K–1 mol–1 (Joule is the unit of work done).
APPEARS IN
RELATED QUESTIONS
Calculate the volume occupied by 8.8 g of CO2 at 31.1°C and 1 bar pressure. R = 0.083 bar L K–1 mol–1.
Which of the following is the correct expression for the equation of state of van der Waals gas?
Compressibility factor for CO2 at 400 K and 71.0 bar is 0.8697. The molar volume of CO2 under these conditions is
Maximum deviation from ideal gas is expected from
Which of the following diagrams correctly describes the behaviour of a fixed mass of an ideal gas? (T is measured in K)
Can a Van der Waals gas with a = 0 be liquefied? explain.
Explain whether a gas approaches ideal behavior or deviates from ideal behaviour if it is compressed to a smaller volume at a constant temperature.
Which of the following gases would you expect to deviate from ideal behavior under conditions of low-temperature F2, Cl2, or Br2? Explain.
A plot of volume (V) versus temperature (T) for a gas at constant pressure is a straight line passing through the origin. The plots at different values of pressure are shown in Figure. Which of the following order of pressure is correct for this gas?
If 1 gram of each of the following gases are taken at STP, which of the gases will occupy (a) greatest volume and (b) smallest volume?
\[\ce{CO, H2O, CH4 , NO}\]
Compressibility factor, Z, of a gas is given as Z = `(pV)/(nRT)`. What is the value of Z for an ideal gas?
Pressure versus volume graph for a real gas and an ideal gas are shown in figure. Answer the following questions on the basis of this graph.
(i) Interpret the behaviour of real gas with respect to ideal gas at low pressure.
(ii) Interpret the behaviour of real gas with respect to ideal gas at high pressure.
(iii) Mark the pressure and volume by drawing a line at the point where real gas behaves as an ideal gas.
Match the following graphs of ideal gas with their co-ordinates:
| Graphical representation | x and y co-ordinates |
(i) ![]() |
(a) pV vs. V |
(ii) ![]() |
(b) p vs. V |
(iii) ![]() |
(c) p vs. `1/V` |
Isotherms of carbon dioxide gas are shown in figure. Mark a path for changing gas into liquid such that only one phase (i.e., either a gas or a liquid) exists at any time during the change. Explain how the temperature, volume and pressure should be changed to carry out the change.



